Carboxylic Acids, Esters, & Amides

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Presentation transcript:

Carboxylic Acids, Esters, & Amides CHAPTER 17 Carboxylic Acids, Esters, & Amides General, Organic, & Biological Chemistry Janice Gorzynski Smith Smith, Janice Gorzynski. General, Organic, & Biological Chemistry 2nd Ed.

CHAPTER 17 Carboxylic Acids, Esters, & Amides Learning Objectives: Identify & describe carboxylic acids, esters, amides Name carboxylic acids, esters, amides Acid/base chemistry of carboxylic acids Formation of esters & amides Hydrolysis of esters & amides Identify polyamides & polyesters CH 17 Homework: End of Chapter problems: Smith, Janice Gorzynski. General, Organic, & Biological Chemistry 2nd Ed.

Examples Carboxylic Acids, Esters, Amides

Reactivity Carboxylic Acids, Ester, Amides

Structure Carboxylic Acids Smith, Janice Gorzynski. General, Organic, & Biological Chemistry 2nd Ed.

Nomenclature Carboxylic Acids 2,4-dimethyl petan oic acid Functional Group Prefix Suffix alkane alkyl ane alkene alkenyl ene alkyne alkynyl yne alcohol (OH) hydroxy ol ether alkoxy halide fluoro, chloro, bromo, iodo thiol (SH) mercapto thiol aldehyde formyl al ketone oxo one carboxylic acid carboxy oic acid carboxylic acid ester oxycarbonyl oate amide carbamoyl O 4 2 1 5 3 OH prefix + parent + suffix prefix First give location and type of substituents. parent How many carbons in longest chain? Carboxylic acid @ C1 What is the functional group? How many? Carboxylic acid: “-oic acid” suffix 2,4-dimethyl petan oic acid * Note: when we have more then 1 functional group the parent name has an “a” added on: hexa instead of hex Smith. General Organic & Biolocial Chemistry 2nd Ed.

Intermolecular Forces Carboxylic Acids

Reactivity Carboxylic Acids

Reactivity Carboxylic Acids

Reactivity Carboxylic Acids