Entropy (S) a measure of disorder

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Presentation transcript:

Entropy (S) a measure of disorder Big Idea 7: The mathematics of probability can be used to describe the behavior of complex systems and to interpret the behavior of quantum mechanical systems. Enduring Understandings (Core concepts that students should retain) 7.B: The tendency of isolated systems to move toward states with higher disorder is described by probability. Essential Knowledge (What students need to know) 7.B.2: The second law of thermodynamics describes the change in entropy for reversible and irreversible processes. Only a qualitative treatment is considered in this course. Entropy, like temperature, pressure, and internal energy, is a state function whose value depends only on the configuration of the system at a particular instant and not on how the system arrived at that configuration. Entropy can be described as a measure of the disorder of a system or of the unavailability of some system energy to do work. 
 The entropy of a closed system never decreases, i.e., it can stay the same or increase. 
 The total entropy of the universe is always increasing. 
 Learning Objectives (What students must be able to do) 7.B.2.1: The student is able to connect qualitatively the second law of thermodynamics in terms of the state function called entropy and how it (entropy) behaves in reversible and irreversible processes.  

https://www.youtube.com/watch?v=YM-uykVfq_E

2nd Law of Thermodynamics (Entropy form) Reversible Process – when the system and its surroundings can return to the exact states they were in before the process. P1 , V1 , T1 P2 , V2 , T2 P1 , V1 , T1 For a Reversible Process S = 0 For an Irreversible Process S > 0 2nd Law of Thermodynamics (Entropy form)

All spontaneous processes are irreversible … heat Since, for any process, the entropy is either constant or increasing, this means that the entropy of the universe is always increasing. Does this make sense??

for a reversible process Recall: for a reversible engine: R for a reversible process

Consider the entropy changes: According the equation S = (Q/T) According to the disorder of each state