Towards Hydrocarbon Analogues of the Porphyrins

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Prepared for: GEOG 4020, Geographic Research Methodology University of Denver, Department of Geography.

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Presentation transcript:

Towards Hydrocarbon Analogues of the Porphyrins Timothy D. Lash, Department of Chemistry, Illinois State University, Normal, IL 61790-4160 Dicarbaporphyrinoids: We have developed three routes for the synthesis of adj-dicarbaporphyrinoid systems with indene, azulene and benzene subunits. A series of dicarbaporphyrinoids have been prepared via fulvene intermediates, and this methodology has been adapted for the synthesis of a 22-oxa-21-carbaporphyrin. In addition, a mesoionic system with two adjacent azulene subunits has been isolated and structurally characterized.