Inverse Photoemission Spectroscopy

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Presentation transcript:

Inverse Photoemission Spectroscopy Base pressure: 5x10-11 mbar Mu metal chamber Manipulator with heating and cooling facility (LN2) Provision for sample transfer Inverse photoemission spectroscopy (IPES) is performed in isochromat mode using acetone/CaF2 band-pass Geiger-counter and Stoffel-Johnson type electron gun. Band-pass of the Geiger counter is determined by the transmission cut-off of CaF2 (10.2 eV) entrance window and photo-ionization threshold of the acetone filling gas (9.7 eV). Thus, only 9.9±0.2eV photons can enter the detector to photoionize the acetone molecules that results in a charge pulse. [Rev. Sci. Instrum., 76, 066102, 2005; Curr. Sci. 90, 490, 2006, Rev. Sci. Instrum, 83, 046107, 2012]. Detector: Works in proportional region, negligible dead time, operates at 730 V, 4 mbar acetone pressure. Electron gun: Focus at 25mm & spot size: 1.4 mm diameter, energy range: 5 to 40 eV. Inside the inverse photoemission spectroscopy (IPES) chamber (a) rotatable and fixed type Stoffel- Johnson type electron sources (b) Photon detector (c) Sample holder with polycrystalline Ag mounted on it. Block diagram of IPES. Experimental inverse photo-emission spectra of - and -brass compared with calculated spectra of Cu, CuZn and Cu Zn with 5% lattice contraction. [Phys. Rev. B 78, 073107 (2008)] IPE spectrum of near stoichiometric Ni2+xMn1-xGa (x=0) at RT in the ferromagnetic and cubic phase, compared with the calculated conduction band structure based on total, Mn, and Ni 3d PDOS. The IPES of x= 0.24 is also shown. [Phys. Rev. B 74, 085110 (2006)] Experimental and calculated inverse photoemission spectra of LaCoO3. [Phys. Rev. B 77,113104 (2008).] Photon detector for IPES with energy resolution of 82 ± 2 meV, best in literature until date. The detector consists of Sr0.7Ca0.3F2 entrance window with energy transmission cutoff of 9.85 eV and acetone as detection gas with 9.7 eV photoionization threshold. The response function of the detector has a nearly Gaussian shape. [Rev. Sci. Instrum., 82, 093901, 2011]. Figure on left compares the response functions of CaF2, MgF2/Kr/CaF2 and Sr0.7Ca0.3F2/ acetone detectors. KRIPS Experimental Station