Mineral Abundances in Martian Soils

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Mineral Abundances in Martian Soils Data from instruments onboard the Mars Exploration Rovers provide researchers with mineralogical details of the average dark soils on the Gusev crater plains and on Meridiani Planum. The procedure uses Mössbauer (MB) data for iron-bearing minerals, Alpha Particle X-ray Spectrometer (APXS) data for iron-absent minerals, and MiniTES thermal infrared spectra for silica and clays. Overview: Using traditional geochemical calculations with in situ Martian cosmochemical data researchers Harry (Hap) McSween Jr. and Ian McGlynn (University of Tennessee) and Deanne Rogers (SUNY at Stony Brook) have developed a method for identifying the major and minor minerals in soils at the Mars Exploration Rovers (MER) landing sites. The team used information from the MER Athena instrument package operating on Mars since January, 2004. They created two models using MiniTES spectra, Alpha Particle X-ray Spectrometer (APXS) data, and Mössbauer spectrometer data to calculate the mineralogy of average dark soils at Gusev crater and Meridiani Planum, located on opposite sides of Mars. Soils at both locations are similarly composed of minerals derived from the comminution of basalts (about three quarters by weight) and other minerals derived from rocks altered by chemical weathering (about one quarter by weight). This mixture of possibly unrelated materials (primary and altered) might mean that the alteration of soil did not occur in place and that the basaltic and alteration suites of minerals came from different sources. The nearly identical modal mineralogy at two widely-separated locations on the planet supports a previous hypothesis based on comparable chemical compositions that soils have been homogenized, if not globally then at least over large areas of the Martian surface. Yet, global maps of orbital remote sensing data have not shown surface abundances of alteration minerals as high as those in the Martian soils. Reference: McSween, Jr., H. Y., McGlynn, I. O., and Rogers, A. D. (2010) Determining the Modal Mineralogy of Martian Soils, Journal of Geophysical Research, v. 115(E00F12), doi: 10.1029/2010JE003582. Caption: Tracks from the MER Opportunity rover cross the soil-covered Martian surface near Victoria Crater (on the horizon) in Meridiani Planum. This approximately-true-color scene was obtained by the rover's panoramic camera (Pancam) in May, 2007.

Mineral Abundances in Martian Soils Soil data from two areas on opposite sides of Mars visited by the MER rovers show that there are more igneous minerals (about 70-85% depending on the model) at each location (Gusev and Meridiani) than alteration minerals (about 15-30%). These percentages may actually bracket the actual mineral abundances. Calculations of the mineralogy of average dark soils from Gusev crater and Meridiani Planum show a predominance of minerals derived from basaltic rocks, about 70-85% depending on the model. The remainder are alteration phases. McSween, McGlynn, and Rogers used two models because they made two different assumptions about the alteration phases involving sulfur and chlorine. Their Model 1 calculates the measured sulfur and chlorine as sulfate and chloride salts. This is consistent with TES and Mini-TES results. Their Model 2 assumes that the sulfur and chlorine are incorporated into or adsorbed onto fine-grained iron oxide minerals (schwertmannite and akaganeite) known to be present in the soils. This model is consistent with Mössbauer measurements. The results likely bracket the actual mineralogy of the soils. The nearly identical modal mineralogy at two locations on opposite sides of the planet supports a prior hypothesis based on similar chemical compositions that soils have been homogenized, at least over large areas of the crust. Yet, global maps of orbital remote sensing data have not shown surface abundances of alteration minerals as high as those identified in the soils by McSween and coauthors. They offer three possible answers. The areal extents of sulfate and clay deposits have not been fully identified from orbit or they have been buried by younger volcanic flows or they have been preferentially weathered and mixed into soils in proportions not representative of the whole surface.