Review
Aromatics Which radical is more stable? Draw structures to show stabilization.
Map out a synthetic route from benzene and/or ethylene.
Stereochemistry Draw the R and S enantiomers of carvone.
Label each chiral center as R/S. Which are enantiomer? Diastereomers?
Which of these compounds are chiral? 2,2,3,3-tetrabromobutane 2,2-dibromo-3,3-dichlorobutane 2,3-dibromo-2,3-dichlorobutane Draw all stereoisomers of the chiral compound and identify the relationships (enantiomers, diastereomers, meso)
Label each chiral center as R/S. Which are enantiomer? Diastereomers?
Assign R/S to each chiral center. Draw sawhorse projections for I and II. Draw skeletal structures for III and IV showing stereochemistry. Identify the stereochemical relationships.
Map out a synthetic route from ethylene What is the configuration of each chiral center? Is it the only product formed?