Review.

Slides:



Advertisements
Similar presentations
Handout #6, 5.12 Spring 2003, 2/28/03 Stereochemistry stereochemistry: study of the spatial characteristics of a molecule stereocenter: atom bonded to.
Advertisements

chemistry in three dimensions
Stereochemistry chemistry in three dimensions. Isomers – different compounds with the same molecular formula. Structural Isomers – isomers that differ.
Chemistry 2100 Lecture 8. Enantiomers Enantiomers: Enantiomers: Nonsuperposable mirror images. –As an example of a molecule that exists as a pair of.
Stereoisomer Descriptor.
Chapter 5: Stereoisomerism
Unit 3 – Stereochemistry
Organic chemistry for medicine and biology students Chem 2311 Chapter 5 Stereochemistry By Prof. Dr. Adel M. Awadallah Islamic University of Gaza.
1 Stereochemistry Prof. Dr. Harno Dwi Pranowo Austrian-Indonesian Center for Computational Chemistry Chemistry Department, FMIPA UGM.
I.1 ii.2 iii.3 iv.4 1+1=. i.1 ii.2 iii.3 iv.4 1+1=
constitutional isomers:
I.1 ii.2 iii.3 iv.4 1+1=. i.1 ii.2 iii.3 iv.4 1+1=
© Prentice Hall 2001Chapter 41 Naming Enantiomers: The R,S System of Nomenclature 1.Rank groups by atomic number of the atom bonded to the chirality center.
Stereochemistry Quiz #4.
Stereoisomerism Nanoplasmonic Research Group Organic Chemistry Chapter 5.
Stereochemistry Stereoisomerism.
Dr. Wolf's CHM 201 & Molecules with Multiple Chirality Centers.
Chapter 4: Stereochemistry. Introduction To Stereochemistry Consider two of the compounds we produced while finding all the isomers of C 7 H 16 : 2-methylhexame.
Stereochemistry The arrangement of atoms in space By: Dr. Manal F. Abou Taleb Organic Chemistry, 5 th Edition L. G. Wade, Jr. chapter 5.
Properties of Stereoisomers of Menthols
Chapter 5: Stereoisomerism Stereoisomers are compounds that have the same structural formula in terms of order of attachment, but differ in arrangements.
Chirality Chirality - the Handedness of Molecules.
Chiral Molecules with Two Stereogenic Centers How many stereoisomers when a particular molecule contains two stereogenic centers?
CHE 311 Organic Chemistry I Dr. Jerome K. Williams, Ph.D. Saint Leo University.
Stereochemistry 1. Stereoisomerism 2. Chirality
CHEM 2411 Review What did you learn in Organic Chemistry I?
Stereochemistry Chiral Molecules
Stereochemistry Unit 8. Stereochemistry Stereochemistry – the study of compound structures in 3 dimensions Stereoisomers – compounds that differ only.
Chapter 5 Stereochemistry: Chiral Molecules 1.
Chemistry 2100 Chapter 15. Enantiomers Enantiomers: Enantiomers: Nonsuperposable mirror images. –As an example of a molecule that exists as a pair of.
Chapter 5 Stereochemistry: Chiral Molecules
Stereochemistry. Stereochemistry: – The study of the three-dimensional structure of molecules Structural (constitutional) isomers: – same molecular formula.
E XPERIMENT 9 Stereochemistry: Enantiomers and Diastereomers.
Stereochemistry Stereochemistry refers to the 3-dimensional properties and reactions of molecules. It has its own language and terms that need to be learned.
Molecules with more than One Chiral Carbon
chemistry in three dimensions
Stereochemistry Chiral Molecules
Diastereomers Stereoisomers:
Stereochemistry Stereochemistry refers to the
Chirality “chiral” Greek for hands chiral =
Compounds with More Than One Chirality Center
P. 289.
Resolution of Enantiomers Part II
University of California,
Chapter 5 Stereochemistry Adel M. Awadallah Islamic University of Gaza
Identify any meso compounds and label any stereocenter R or S.
Supplemental Instruction
Chapter 5 Stereochemistry Adel M. Awadallah Islamic University of Gaza
Only three of a maximum possible four stereoisomers exists for the molecule shown. These include a pair of enantiomers and a single meso compound. Meso.
Chapter 5: Stereochemistry
Maximum Stereoisomers for 2,3-dibromobutane? (2S,3R) (2R,3R) (2R,3S)
Chirality “chiral” Greek for hands chiral =
Chapter 5 Stereochemistry: Chiral Molecules
Chapter 9 Stereochemistry.
CH 5-6: Meso Compounds – A new type of Stereoisomer
Chirality “chiral” Greek for hands chiral =
ENANTIOMERIC PAIR mirror images NOT superimposable
Islamic University of Gaza
Chapter 7 STEREOCHEMISTRY
CH 5-3: A new Stereoisomer - Diastereomers
1. Perspective Formulas.
Stereoisomerism and Chirality Unit 6.
Unit 3 – Stereochemistry
Isomers: The Arrangement of Atoms in Space University of California,
Chapter 4: Stereochemistry
enantiomers and diastereomers
Chapter 5 Stereochemistry Adel M. Awadallah Islamic University of Gaza
Stereochemistry.
Chapter 5 Stereochemistry Adel M. Awadallah Islamic University of Gaza
Presentation transcript:

Review

Aromatics Which radical is more stable? Draw structures to show stabilization.

Map out a synthetic route from benzene and/or ethylene.

Stereochemistry Draw the R and S enantiomers of carvone.

Label each chiral center as R/S. Which are enantiomer? Diastereomers?

Which of these compounds are chiral? 2,2,3,3-tetrabromobutane 2,2-dibromo-3,3-dichlorobutane 2,3-dibromo-2,3-dichlorobutane Draw all stereoisomers of the chiral compound and identify the relationships (enantiomers, diastereomers, meso)

Label each chiral center as R/S. Which are enantiomer? Diastereomers?

Assign R/S to each chiral center. Draw sawhorse projections for I and II. Draw skeletal structures for III and IV showing stereochemistry. Identify the stereochemical relationships.

Map out a synthetic route from ethylene What is the configuration of each chiral center? Is it the only product formed?