Starter S-55 What is the value of a mole? What is that number used for?

Ionic and Metallic Bonding Chapter 7 Ionic and Metallic Bonding

Chapter 7 7.1 Ions

7.1 Ions Valence Electrons – highest energy electrons Groups always have the same number of valence electrons

7.1 Ions Valence electrons are related to the group Valence electrons are usually the ones involved in chemical bonding

7.1 Ions Octet Rule Metals tend to lose their valence electrons leaving a complete octet in the next lowest energy level Nonmetals tend to gain or share electrons to complete their octet Ionic Bonding

7.1 Ions Ionic Bonding involves the formation of a Cation – lose electrons Anions – gain electrons Formation of Ions

Al+3 Al 7.1 Ions Electron configuration change in cation formation 3s 3p 3d 2s 2p 1s Lower Octet

S-2 S 7.1 Ions Electron configuration change in anion formation 3s 3p 3d 2s 2p 1s New Octet

7.1 Ions Oxidation Number – apparent charge in a compound

Starter S-57 Draw the noble gas configuration for Phosphorus [Ne]3s23p3 Predict the oxidation number. P-3

7.2 Ionic Bonds and Ionic Compounds Chapter 7 7.2 Ionic Bonds and Ionic Compounds

7.2 Ionic Bonds and Ionic Compounds Ionic Compounds – composed of cations and anions One element give electrons to the other element

7.2 Ionic Bonds and Ionic Compounds Writing formulas for ionic compounds The sum of the charges always equals 0 Usually if we flip the number values So the formula would be

7.2 Ionic Bonds and Ionic Compounds Positive ion is always written first Numbers are written after the element and as a subscript The number 1 is never written

7.2 Ionic Bonds and Ionic Compounds Try Aluminum and Oxygen Calculations Formula

7.2 Ionic Bonds and Ionic Compounds Formulas are always given as smallest ratio so Calculations Formula Pb+4 O-2

7.2 Ionic Bonds and Ionic Compounds Formula Unit – the smallest whole number ratio of ions Ionic Compounds are really repeating structures

7.2 Ionic Bonds and Ionic Compounds Properties of Ionic Compounds Most are crystalline solids at room temperature Generally have high melting points Conduct an electric current when melted or dissolved

Chapter 7 7.3 Bonding in Metals

7.3 Bonding in Metals In metals valence electrons are free to move around The individual atoms are free to slide past each other Explains conductivity – electrons are free to move Bonding Animation

Starter S-59 Draw the noble gas configuration for Oxygen and Indium (In) [He]2s22p4 , [Kr]5s24d105p1 Predict the oxidation number. O-2, In+3 What will be the formula of the compound they form? In2O3

7.3 Bonding in Metals Ductility and Malleability – metals free to slide past each other Metals are arranged in compact and orderly crystal patterns Body Centered Cubic-every atom has eight neighbors Na, K, Fe, Cr, W Crystal Structures

7.3 Bonding in Metals Face Centered Cubic – every atom has 12 neighbors Cu, Ag, Au, Al, Pb Hexagonal Close Packed – 12 different pattern Mg, Zn, Cd

7.3 Bonding in Metals Alloys – mixtures composed two or more elements, at least one of which is a metal Sterling silver 92.5% silver, 7.5% copper Harder, more durable than Ag Bronze 87.5% copper, 12.5% tin Harder, more easily cast

7.3 Bonding in Metals Steel Stainless Steel (80.6% Fe, 18.0% Cr, 0.4% C, 1.0 % Ni) Spring Steel (98.6% Fe, 1.0% Cr, 0.4% C)

7.3 Bonding in Metals Surgical Steel (67% Fe, 18% Cr, 12% Ni, 3% Mo)

Starter S-60 Draw the noble gas configuration for Chlorine and Antimony [Ne]3s23p5 , [Kr]5s24d105p3 Predict the oxidation number. Cl-1, Sb+5 What will be the formula of the compound they form? SbCl5

Starter S-62 Predict the chemical formula of a compound made with Oxygen and Silver AgNO3 Tungston and Chlorine WCl2 Aluminum and Sulfur Al2S3