A Simple Molecular Machine Operated by Photoinduced Proton Transfer

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Presentation transcript:

A Simple Molecular Machine Operated by Photoinduced Proton Transfer 1 J. AM. CHEM. SOC. 2007, 129, 13378-13379 Serena Silvi,† Arturo Arduini,‡ Andrea Pochini,‡ Andrea Secchi,‡ Massimiliano Tomasulo,§ Francisco M. Raymo,§ Massimo Baroncini,† and Alberto Credi*† Dipartimento di Chimica “G. Ciamician”, UniVersita` di Bologna, Via Selmi 2, 40126 Bologna, Italy, Dipartimento di Chimica Organica e Industriale, UniVersita` di Parma, Via Usberti 17/a, 43100 Parma, Italy, and Center for Supramolecular Science, Department of Chemistry, UniVersity of Miami, 1301 Memorial DriVe, Coral Gables, Florida 33146-0431 † Universita´ di Bologna. ‡ Universita´ di Parma. § University of Miami.

2 The threading−dethreading of a photoinactive pH-switchable calix[6]arene bipyridinium pseudorotaxane in solution has been controlled by visible light irradiation using a merocyanine compound as a photoacid. The coupling between the two molecular switches that communicate with one another by intermolecular proton transfer provides a general principle for the operation of acid−base controllable molecular machines with light.

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8 Figure 1. Pseudorotaxane [C*AH]2+, black curve; (ii) [C*AH]2+ and SP, immediately after the addition of the latter, blue curve; (iii) solution (ii) after 7 days of rest in the dark, red curve; (iv) solution (iii) after 10 min of irradiation (> 450 nm), green curve. Inset: absorbance changes at 417 nm (a) and 550 nm (b) of a solution containing [C*AH]2+ and SP observed upon several cycles of thermal equilibration (7 days in the dark at room temperature, white areas) and visible light irradiation (10 min with a 150 W tungsten-halogen lamp, ì > 450 nm, gray areas). The concentration was 1.0 10-4 M.

In conclusion, they have shown that the threading-dethreading of a pH-switchable calix[6]arene bipyridinium pseudorotaxane in solution can be controlled by visible light irradiation using a merocyanine compound as a photoacid. Such a coupling between the two molecular switches that communicate with one another by intermolecular proton transfer provides a general principle for the operation of photoinactive acid-base controllable molecular machines with light.