Intermolecular Forces, Liquids, and Solids Chapter 11/12

Warmup: Phase Changes What is the vocabulary used with phase changes? What happens in a phase change at the particle level?

Intermolecular Forces vs. Intramolecular Forces

Intermolecular Forces The stronger the attractive forces in a liquid, the higher the boiling point The stronger the attractive forces in a solid, the higher the melting point

Intermolecular Forces Dipole-Dipole Force, London Dispersion forces, and hydrogen bonding forces A fourth force is an Ion-Dipole Force All four forces are electrostatic and tend to be less than 15% as strong as an ionic or covalent bond

Ion-Dipole Forces exist between the ion and the partial charge on the end of a polar molecule important in solutions

Dipole-Dipole Forces Neutral polar molecules attract to each other when the positive end of one molecule is near the negative end of another Strength depends on polarity Weaker than ion-dipole forces

London Dispersion Forces the motion of electrons in an atom or molecule can create an instantaneous dipole moment

London Dispersion Forces Strength of force is based on polarizability Polarizability increases with increasing molecular weight and complexity of shape LDF’s exist between all molecules, polar and nonpolar

Which of these substances has greater London dispersion attractions? Sample Exercise 11.1 Comparing Intermolecular Forces The dipole moments of acetonitrile, CH3CN, and methyl iodide, CH3I, are 3.9 D and 1.62 D, respectively. Which of these substances has greater dipole–dipole attractions among its molecules? Which of these substances has greater London dispersion attractions? The boiling points of CH3CN and CH3I are 354.8 K and 315.6 K, respectively. Which substance has the greater overall attractive forces?

Of Br2, Ne, HCl, HBr, and N2, which is likely to have Sample Exercise 11.1 Comparing Intermolecular Forces Of Br2, Ne, HCl, HBr, and N2, which is likely to have (a) the largest london dispersion forces, (b) the largest dipole–dipole forces?

Hydrogen Bonding Considered a unique dipole-dipole interaction Force between the H atom in a polar bond (H-F, H-O, or H-N) and an unshared electron pair on a nearby electronegative ion or atom(usually N,F, or O) Stronger than dipole-dipole or dispersion forces

Hydrogen Bonding

Sample Exercise 11.2 Identifying Substances that Can Form Hydrogen Bonds In which of the following substances is hydrogen bonding likely to play an important role in determining physical properties: CH4, H2NNH2, CH3F, H2S,CH2Cl2, H2O2, CH3COCH3, PH3 ?

Identify the attractive forces between the following:

Comparing Intermolecular Forces

Sample Exercise 11.3 Predicting the Types and Relative Strengths of Intermolecular Attractions List the substances H2, CO, HF, and Ne in order of increasing boiling points. Identify IMF’s present in the following substances and order their bp: CH3CH3, CH3OH, and CH3CH2OH.

Properties of Liquids Viscosity is the resistance of a liquid to flow Stronger IMF, higher viscosity

Properties of Liquids Surface tension is the energy required to increase the surface area of a liquid by a unit amount. A force is pulling molecules from the surface inward. Stronger IMF’s, stronger surface tension.

Phase Changes

accompanied by a change in energy of the system Phase Changes accompanied by a change in energy of the system

Heating Curves Graph of the temperature of the system versus the amount of heat added.

Vapor pressure Pressure exerted by a vapor in equilibrium with the liquid phase A liquid boils when its vapor pressure equals the external pressure acting on the surface of the liquid

Phase Diagrams graphical way to summarize the conditions under which equilibrium exists between different states of matter

General Phase Diagram Includes three important curves which represent temperatures and pressures where the various phases can co-exist

General Phase Diagram The line from A to B is the vapor pressure curve. It represents the equilibrium between the liquid and gas phase. The normal bp is found at 1 atm on this curve

General Phase Diagram Point B is where the critical P and T are found Beyond the critical point the liquid and gas phase are indistinguishable

General Phase Diagram The line AD represents the equilibrium between the solid and liquid The mp and fp are identical, and differ only in direction The normal mp is at 1 atm

General Phase Diagram Line AC represents the equilibrium between solid and gas Point A is the Triple Point, where the three phases intersect and are at equilibrium

Phase Diagram – special cases The mp of water decreases with increasing pressure because the liquid form is more compact than the solid form. There is no normal mp in CO2. At 1 atm pressure, the substance will sublime

Sample Exercise 11.6 Interpreting a Phase diagram Describe any changes in the phases present when H2O is kept at 0 °C while the pressure is increased from that at point 1 to that at point 5 (b) kept at 1.00 atm while the temperature is increased from that at point 6 to that at point 9

Structures of Solids Crystalline Solids Atoms, ions, or molecules are ordered in a well-defined three-dimensional arrangements; they have flat surfaces or faces and regular shapes Quartz and diamond are crystalline solids

Structures of Solids Amorphous Solids Solids in which particles have no orderly structure; lack faces and shape Rubber and glass are amorphous solids

Structures of Solids

Bonding in Solids - Molecular Solids Atoms or molecules (nonmetals) held together by IMF’s Soft, low mp, poor conductors

Bonding in Solids – Covalent-Network Solids Atoms held together in large networks or chains by covalent bonds Hard, high mp, variable conductors

Bonding in Solids - Ionic Solids Ions held together by ionic bonds (electrostatic forces) Hard, brittle, high mp, poor conductors

Bonding in Solids - Metallic Solids Metal atoms Visualize the metals as an array of positive ions immersed in a sea of delocalized valence electrons soft to very hard, low to high mp, excellent conductors, malleable and ductile

Alloys Mixture of elements exhibiting metallic properties

Summary of Bonding in Solids