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Copyright © by Houghton Mifflin Company. All rights reserved. Chapter 3 Stoichiometry Copyright © by Houghton Mifflin Company. All rights reserved.

Measurement of Atomic Mass Most elements occur in nature as mixture of isotopes; thus atomic masses are usually average values. The modern system of atomic masses, instituted in 1961, is based on 12C as the standard. In this system 12C is assigned a mass of exactly 12 atomic mass units (amu), and the masses of all other atoms are given relative to this standard. Copyright © by Houghton Mifflin Company. All rights reserved.

Copyright © by Houghton Mifflin Company. All rights reserved. Mass spectrometer Copyright © by Houghton Mifflin Company. All rights reserved.

Copyright © by Houghton Mifflin Company. All rights reserved. Atomic Mass of Carbon 12C and 13C are analyzed in a mass spectrometer, the ratio of their masses is found to be: Mass 13C/Mass 12C=1.0836129 Mass of 13C=(1.0836129)(12amu)=13.003355 amu The natural carbon is composed of 98.89% 12C atoms and 1.11% 13C atoms. (0.9889)(12 amu)+(0.0111)(13.0034 amu)=12.01 amu Copyright © by Houghton Mifflin Company. All rights reserved.

Copyright © by Houghton Mifflin Company. All rights reserved. Peaks of neon injected Copyright © by Houghton Mifflin Company. All rights reserved.

Bar graph of neon injected Copyright © by Houghton Mifflin Company. All rights reserved.

Percent Composition of Compounds 1 mole C2H5OH Mass of C=2 mol X 12.011g/mol=24.022 g Mass of H=6 mol X 1.008 g/mol=6.048 g Mass of O=1 mol X 15.999 g/mol=15.999 g Mass of 1 mol of C2H5OH=46.069 g Mass percent of C=(24.022/46.069)x100%=52.144% Mass percent of H=(6.048/46.069)X100%=13.13% Mass percent of O=(15.999/46.069)X100%=34.728% Copyright © by Houghton Mifflin Company. All rights reserved.

Determining the Formula of a Compound Copyright © by Houghton Mifflin Company. All rights reserved.

Copyright © by Houghton Mifflin Company. All rights reserved. Chemical Equations Need to know the reactants and products Balancing a chemical equation Specify the physical states of the reactants and products Stoichiometric calculations Calculations involving a limiting reaction Copyright © by Houghton Mifflin Company. All rights reserved.