The Distribution of Molecular Speeds

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Presentation transcript:

The Distribution of Molecular Speeds Maxwell’s speed distribution law:

Internal Energy Eint Translational Kinetic Energy: Molar Specific Heats at Constant Volume Molecule Example CV (J/mol · K) Monatomic Ideal Real He 12.5   Ar 12.6 Diatomic N2 20.7 O2 20.8 Polyatomic 3R = 24.9 NH4 29.0 CO2 29.7

Molar Specific Heats a. at Constant Volume b. at Constant Pressure

The Adiabatic Expansion of an Ideal Gas

Proof of:

Graphical Summary of Four Gas Processes Equations Valid for all paths: Path Constant Quantity Process Type Some Special Results