Types of Chemical Reactions and Solution Stiochiometry Chapter 4 Types of Chemical Reactions and Solution Stiochiometry

Preview the contents of this chapter will introduce you to the following topics: Water, Nature of aqueous solutions, types of electrolytes, and dilution Types of chemical reactions: precipitation, acid base reactions and oxidation-reduction reaction Stoichiometry of reactions and balancing the chemical equations Morsy CHEM 101 Chapter 4

4.1 Water, the Common Solvent Water is one of the most important substances on earth: Cooling – engine, nuclear power plants, and many. Transportation …etc. Water dissolve many different substances, e.g. salts, sugar, and many other To understand this process, we need to consider the nature of water: As molecule, is H2O Shape is V-shape with angle 105o Band type of each O – H is covalent band and polar [electrons are not equirdlntty shared] Polarity is polar with +ve charges of hydrogen and -ve on oxygen. This Polarity of water gives it the greatest ability to dissolve compounds. Morsy CHEM 101 Chapter 4

4.1 Water, the Common Solvent This Polarity of water gives it the greatest ability to dissolve compounds. Figure 4.2 shows schematic ionic solid dissolving in water. This process is called "Hydration". Note: The stronger the ion-water attraction, the higher the solubility. Therefore, not all the solid have the same solubility [chapter 11]. Morsy CHEM 101 Chapter 4

4.1 Water, the Common Solvent Water also dissolve non-ionic substances e.g. alcohols – "polar" and compatible structure to water: "like – dissolve – like" Figure 4.3 many substances don't dissolve in water e.g. animal fats "non-polar" Morsy CHEM 101 Chapter 4

4. 2 The Nature of Aqueous Solutions: 4.2 The Nature of Aqueous Solutions: Strong and Weak Electrolytes & non–Electrolyte Solution – composite of solute (substance to be dissolved) + Solvent (Major substance e.g. water). Solute: Solvent: dissolves in water (or other “solvent”) changes phase (if different from the solvent) is present in lesser amount (if the same phase as the solvent) retains its phase (if different from the solute) is present in greater amount (if the same phase as the solute) Solution Solvent Solute Soft drink (l) H2O Sugar, CO2 Air (g) N2 O2, Ar, CH4 Soft Solder (s) Pb Sn Morsy CHEM 101 Chapter 4

4. 2 The Nature of Aqueous Solutions: 4.2 The Nature of Aqueous Solutions: Strong and Weak Electrolytes & non–Electrolyte One major property for characterizing aqueous solutions is its "Electrical conductivity" or its ability to conduct an electric current. Three solutions are observed: non electrolytes, weak, electrolytes and strong electrolyte. figure 4.4 The basis for conductivity properties of solutions was first correctly identified by Svante Arrhenius (1859 – 1927) nonelectrolyte weak electrolyte strong electrolyte An electrolyte is a substance that, when dissolved in water, results in a solution that can conduct electricity. Morsy CHEM 101 Chapter 4

NaCl (s) Na+ (aq) + Cl- (aq) 4.2 The Nature of Aqueous Solutions: Strong and Weak Electrolytes & non–Electrolyte Arrhenius postulated that the electric current depend directly on the number of ions present. Strong Electrolyte – 100% dissociation NaCl (s) Na+ (aq) + Cl- (aq) H2O Weak Electrolyte – not completely dissociated CH3COOH CH3COO- (aq) + H+ (aq) Nonelectrolyte does not conduct electricity? No cations (+) and anions (-) in solution C6H12O6 (s) C6H12O6 (aq) H2O Morsy CHEM 101 Chapter 4

4.3 The Composition of Solutions: To perform stoichiomctric calculations at any chemical reactions you must know two things: The nature of the reaction – exact forms of chemical in solutions. The amounts of chemicals – "concentration" concentration of a solution can be described in many different ways, % , molar, molal, mole. faction .. etc. We will consider here the unit "molar"(M) or molarity: "the method used to prepare molar solutions". Molarity (M) = moles of solute per volume of solution in liters: Morsy CHEM 101 Chapter 4

Moles = Liters of solution x Molarity. 4.3 The Composition of Solutions: Notes: For ionic systems the solution prepared will contain the number of moles prepared but for ionic species its different story e.g. 1.0M NaCl contains 1.0 mole NaCl or more accurate 1.0 mole of Na+ and 1.0 mole of Cl-. Molarity can be used to determine number of moles per certain volumes where: Moles = Liters of solution x Molarity. Example 4.3 Gives the concentration of each type of ion in the solutions of 0.50M Co(NO3)2 Example 4.4 Calculate the number of moles of Cl- ions in 1.75 L of 1.0x10-3M ZnCl2 Morsy CHEM 101 Chapter 4

4.3 The Composition of Solutions: Standard Solution: Solution used in chemical analysis. it has accurately known concentration Dilution: it is the procedure to get low concentrated solution (diluted) from a high concentrated one. Moles of solute after dilution = moles of solute before dilution. (M x V) after = (M x V) before. Example 4.7 What volume of 16 M sulfuric Acid must be used to prepare 1.5 L of a 0.10M H2sO4 solution? Morsy CHEM 101 Chapter 4

Precipitation reactions Acid-base reactions 4.4 Types of Solution Reactions Millions of possible chemical reaction needs system for grouping them into classes. The commonly used by chemists: Precipitation reactions AgNO3(aq) + NaCl(aq)  AgCl(s) + NaNO3(aq) Acid-base reactions NaOH(aq) + HCl(aq)  NaCl(aq) + H2O(l) Oxidation-reduction reactions Fe2O3(s) + Al(s)  Fe(s) + Al2O3(s) Morsy CHEM 101 Chapter 4

4.5 Precipitation Reactions Precipitate – insoluble solid that separates from solution PbI2 precipitate Pb(NO3)2 (aq) + 2NaI (aq) PbI2 (s) + 2NaNO3 (aq) molecular equation Pb2+ + 2NO3- + 2Na+ + 2I- PbI2 (s) + 2Na+ + 2NO3- ionic equation Pb2+ + 2I- PbI2 (s) net ionic equation Na+ and NO3- are spectator ions Morsy CHEM 101 Chapter 4

Simple Rules for Solubility of Aq. Solutions 4.5 Precipitation Reactions Simple Rules for Solubility of Aq. Solutions 1. Most nitrate (NO3) salts are soluble. 2. Most alkali (group 1A) salts and NH4+ are soluble. 3. Most Cl, Br, and I salts are soluble (NOT Ag+, Pb2+, Hg22+) Most sulfate salts are soluble (Except BaSO4, PbSO4, HgSO4, CaSO4) Most OH salts are only slightly soluble (Except NaOH, KOH are soluble) 6. Most S2, CO32, CrO42, PO43 salts are only slightly soluble, i.e., Not soluble. Exercise 4.8: Using the solubility rules in table 4.1, predict what will happen when the following pairs of solutions are mixed. KNO3(aq) & BaCl2(aq) Na2SO4(aq) & Pb(NO3)2(aq) KOH(aq) & Fe(NO3)(aq) Morsy CHEM 101 Chapter 4

Writing Net Ionic Equations 4.6 Describing Reactions in Solution Writing Net Ionic Equations Write the balanced molecular equation. Write the ionic equation showing the strong electrolytes Determine precipitate from solubility rules Cancel the spectator ions on both sides of the ionic equation Write the net ionic equation for the reaction of silver nitrate with sodium chloride. AgNO3 (aq) + NaCl (aq) AgCl (s) + NaNO3 (aq) Ag+ + NO3- + Na+ + Cl- AgCl (s) + Na+ + NO3- Ag+ + Cl- AgCl (s) Morsy CHEM 101 Chapter 4

4.7 Stoichiometry of Precipitation Reactions The procedures for calculating quantities of reactants and products involved in chemical reaction. The following steps summarized the procedure: Step 1: Identify the present in the combined solution, and determine what reaction occurs. Step 2: write the balanced net ionic equation. Step 3: calculate the moles of reactants. Step 4: determine which reactant is limiting. Step 5: calculate the moles of product or product as required. Step 6: convert to grams or other units, as requires. Example 4.11 When aqueous solutions of Na2SO4 and Pb(NO3)2 are mixed, PbSO4 precipitates. Calculate the mass of PbSO4 formed when 1.25L of 0.0500M Pb(NO3)2 and 2.00L of 0.0250M Na2SO4 are mixed. Morsy CHEM 101 Chapter 4

4.8 Acid – Base Reactions: Acids Bases Have a bitter taste. Have a sour taste. Vinegar owes its taste to acetic acid. Citrus fruits contain citric acid. React with certain metals to produce hydrogen gas. React with carbonates and bicarbonates to produce carbon dioxide gas Bases Have a bitter taste. Feel slippery. Many soaps contain bases. Morsy CHEM 101 Chapter 4

4.8 Acid – Base Reactions: Arrhenius acid is a substance that produces H+ (H3O+) in water Arrhenius base is a substance that produces OH- in water Morsy CHEM 101 Chapter 4

4.8 Acid – Base Reactions: A Brønsted acid is a proton donor A Brønsted base is a proton acceptor base acid acid base A Brønsted acid must contain at least one ionizable proton! Morsy CHEM 101 Chapter 4 4.3

4.8 Acid – Base Reactions: They are also called neutralization reaction acid + base salt + water Describing Reactions in Solution HCl (aq) + NaOH (aq) NaCl (aq) + H2O H+ + Cl- + Na+ + OH- Na+ + Cl- + H2O H+ + OH- H2O Morsy CHEM 101 Chapter 4 4.3

x acid + y base salt + water 4.8 Acid – Base Reactions: They are also called neutralization reaction x acid + y base salt + water Main reaction is titration, the key terms are: Titrant - solution of known concentration used in titration Analyte - substance being analyzed Equivalence point - enough titrant added to react exactly with the analyte Endpoint - the indicator changes color so you can tell the equivalence point has been reached. The neutralization reaction calculation: a. Write the correct balanced acid–base reaction. b. Use the following equation: y. (M.V)acid = x. (M.V)base Morsy CHEM 101 Chapter 4 4.3

Equivalence point – the point at which the reaction is complete 4.8 Acid – Base Reactions: In a titration a solution of accurately known concentration is added gradually added to another solution of unknown concentration until the chemical reaction between the two solutions is complete. Equivalence point – the point at which the reaction is complete Indicator – substance that changes color at (or near) the equivalence point Slowly add base to unknown acid UNTIL the indicator changes color Morsy CHEM 101 Chapter 4 4.7 4.3

4.9 Oxidation-Reduction Reactions: (electron transfer reactions) 2Mg (s) + O2 (g) 2MgO (s) 2Mg 2Mg2+ + 4e- Oxidation half-reaction (lose e-) O2 + 4e- 2O2- Reduction half-reaction (gain e-) 2Mg + O2 + 4e- 2Mg2+ + 2O2- + 4e- 2Mg + O2 2MgO Morsy CHEM 101 Chapter 4

4.9 Oxidation-Reduction Reactions: Morsy CHEM 101 Chapter 4 4.4

4.9 Oxidation-Reduction Reactions: Rules for Assigning Oxidation States 1. Oxidation state of an atom in an element = 0 2. Oxidation state of monatomic element = charge 3. Oxygen = 2 in covalent compounds (except in peroxides where it = 1) 4. H = +1 in covalent compounds 5. Fluorine = 1 in compounds 6. Sum of oxidation states = 0 in compounds Sum of oxidation states = charge of the ion IF7 Oxidation numbers of the elements in the following ? F = -1 7x(-1) + ? = 0 I = +7 Morsy CHEM 101 Chapter 4 4.4

4.10 Balancing Oxidation – Reduction Equations Balancing by Half-Reaction Method (Acidic) 1. Write separate reduction, oxidation reactions 2. For each half-reaction: Balance elements (except H, O) Balance O using H2O Balance H using H+ Balance charge using electrons 3. If necessary, multiply by integer to equalize electron count 4. Add half-reactions 5. Check that elements and charges are balanced Morsy CHEM 101 Chapter 4

4.10 Balancing Oxidation – Reduction Equations Half-Reaction Method - Balancing in Base 1. Balance as in acid. 2. Add OH- that equals H+ ions (both sides!) 3. Form water by combining H+, OH- 4. Check elements and charges for balance Morsy CHEM 101 Chapter 4