HBr Relevant to the HBr-FvsV state paper: https://notendur.hi.is/agust/rannsoknir/rempi/hbr/Jan12/PPT-130212ak.ppt https://notendur.hi.is/agust/rannsoknir/rempi/hbr/Jan12/XLS-130212ak.xls.

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HBr Relevant to the HBr-FvsV state paper: https://notendur.hi.is/agust/rannsoknir/rempi/hbr/Jan12/PPT-130212ak.ppt https://notendur.hi.is/agust/rannsoknir/rempi/hbr/Jan12/XLS-130212ak.xls https://notendur.hi.is/jil3/work/Paper/HBr_FvsV/BWs%20for%20HBr_FvsV.xlsx

Model: 1/t0E1 E1 1/tE1 1/t0H0 H0 1/tF1 1/t0F1 V7 F1 1/tH0 1/tother Assume:

Linewidths https://notendur.hi.is/jil3/work/Paper/HBr_FvsV/BWs%20for%20HBr_FvsV.xlsx

Bw vs lifetime comparisons 79 J´=6 J´=3 states: Bw/cm-1 t(ps)= 1/t (ps-1) rate const. Sums fraction V7 7.80613 ca. 0.678954 1.472855 1 4.26927 1.24143 0.805523 ? E1 4.73001 > 1.120505 0.892455 0.605935 3.87256 1.368604 0.730672 0.907078 F1 1.4125 >> 3.752212 0.266509 0.180948 1.00749 5.260598 0.190092 0.235986 H0 1.23787 4.281548 0.23356 1.392525 E1+F1+H0 0.158577 1.187274 0.330853 diff/others: 12.44862 0.08033 0.05454 -0.38175 J´=5(?) J´=4 8 guess! 0.6625 1.509434 7.6149 0.696004 1.436774 4.87403 1.087396 0.919628 0.609254 4.68442 1.13141 0.883853 0.615165 1.44447 3.669166 0.272542 0.180559 1.18607 4.468539 0.223787 0.155756 1.12631 4.705632 0.212511 1.404681 0.140789 1.16461 4.55088 0.219738 1.327377 0.152938 9.546281 0.104753 0.069399 9.141083 0.109396 0.07614 https://notendur.hi.is/agust/rannsoknir/rempi/hbr/Jan12/XLS-130212ak.xls

Bw vs lifetime comparisons 81 J´=6 J´=3 states: Bw/cm-1 t(ps)= 1/t (ps-1) rate const. Sums fraction V7 7.80613 ca. 0.678954 1.472855 1 ? 4.26927 1.24143 0.805523 E1 3.30123 > 1.605462 0.622874 0.422902 3.76181 1.408896 0.709775 0.881137 F1 1.58492 >> 3.344017 0.299042 0.203035 1.31921 4.017556 0.248908 0.309001 H0 1.35547 3.910083 0.255749 1.177664 E1+F1+H0 0.173642 1.39211 3.80717 0.262662 1.221345 0.326077 diff/others: 3.387642 0.295191 0.200421 -0.41582 J´=5(?) J´=4 8.525 guess! 0.621701 1.608491 7.6149 0.696004 1.436774 4.97777 1.064734 0.939202 0.583903 3.94064 1.344959 0.743517 0.517491 2.32178 2.282731 0.438072 0.27235 1.70066 3.116437 0.320879 0.223333 1.22425 4.329181 0.230991 1.608264 0.143607 1.25774 4.213907 0.237309 1.301706 0.165168 4416.667 0.000226 0.000141 7.403682 0.135068 0.094008 https://notendur.hi.is/agust/rannsoknir/rempi/hbr/Jan12/XLS-130212ak.xls

In summary: according to J´=4 and 6: i = 79 & 81 : rates ca. 1/tV7 = 1.47 ps-1 1/t0E1 E1 1/tE1 = 0.83 ps-1 1/t0H0 1/tF1 =0.27 H0 1/t0F1 1/tH0 =0.23 ps-1 V7 F1 1/tother =0.11 ps-1

In summary: according to J´=4 and 6: i = 79& 81 : fractional rates ca Rel. 1/tV7 = 1 1/t0E1 E1 Rel. 1/tE1 = 0.58 Rel. 1/tF1 =0.19 1/t0H0 H0 1/t0F1 Rel. 1/tH0 =0.16 V7 F1 1/tother =0.07