Solubility Guidelines and Predicting precipitates

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Presentation transcript:

Solubility Guidelines and Predicting precipitates Chem 12 Mrs. Kay

Solubility Guidelines Summary of ionic-compounds interactions with water The table breaks down the ionic compound into cation and anions and describes its level of solubility. If it is soluble it will completely break up into its ions. If it is insoluble it will not break up into ions, but remain the same compound.

NO– SO4 2– OH– Cl– Br– I– S 2– C2H3O 2– CO3 2– PO4 3– Na+ K+ NH4+ Ag+ ss - I Al3+ d Ba2+ Ca2+ Co2+ Cu2+ Hg2+ Mg2+ Pb2+ Sr2+ Zn2+ S= soluble ss = slightly soluble I = insoluble d = decomposes in water

Practice: Using your solubility tables from your data booklets, tell me if the following compounds will break up in water, or remain the same. PbCl2 ZnO AgCH3COO KNO3 CaCO3 AlPO4 AgCl ZnCO3 FeSO4 MgCl2 CaS

Mix two aqueous ionic compounds… Two possibilities: Compounds will remain in solution without reacting Compounds will react with one another, producing new products. HOW CAN YOU TELL WHAT WILL HAPPEN?

Double Displacement Reactions WX + YZ  WZ + YX You know its happened if: Forms a precipitate (ions makes an insoluble solid) Forms a gas (ions make a gas product) Forms water (H+ and OH- combine)

In other words… If all the reactants are soluble, even after a replacement has occurred and you have not formed a precipitate, a gas, or water, then no reaction has occurred. It would look like: NH4Cl + ZnSO4  NR NH4+ + Cl- + Zn+2 + SO4-2  when combined it only makes soluble compounds, so no reaction

Ag+(aq) + Cl-(aq)  AgCl(s) Balanced Equation: AgNO3(aq) + NaCl(aq)  AgCl(s)+ NaNO3(aq) Ionic Equation: (soluble compounds break up into ions, otherwise stay the same) Ag+(aq) + NO3-(aq) + Na+(aq) + Cl-(aq)  AgCl(s) + Na+(aq) + NO3-(aq) Net Ionic Equation: cancel out spectator ions (ones that are the same on both sides) Ag+(aq) + Cl-(aq)  AgCl(s)