Announcements Be respectful – no electronics please!

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Announcements Be respectful – no electronics please! Exam 1 – Tuesday February 12th, 7:00 pm Pre & Post-lecture Assignments (Lon-Capa) 8 am next Thursday Lab write-up 2 due tomorrow in discussion Textbook homework Assignment 4 due tomorrow in discussion (pg. 16) Review Questions Part 1 Due Friday at 10:00 pm in Lon-Capa (will work on during discussion)

Joke of the Day What kind of dog do chemists have? Laboratory retrievers!

Exam Info – February 12th Be respectful – no electronics please! Conflict exam: Same day 5-6:30 pm Sign up in 1026 Chem Annex by noon on 2/12 Please email me if you have a conflict with both the regular exam and the conflict exam. Practice Exams posted online! My Question & Answer Session this weekend: Sunday 5-6 pm in 217 Noyes You may use a calculator (NOT TI-Nspire.)

Exam 1 Topics Major Topics Minor Topics Matter Naming The mole Memorize polyatomics, especially those ending in “-ate”, hydroxide, ammonium The mole Empirical & molecular formula Gases & related problems Isotopes & ions (protons, neutrons, electrons) Conversion problems Density Chemical & physical changes Not Tested Significant Figures

Exam Format – 90 minutes total 15 Multiple Choice Questions 2 Free Response Questions 5 possible choices 50% of test grade ~3 minutes to answer each (~45 min on this half of exam) Write in answers – both qualitative and quantitative 50% of test grade ~45 minutes on this half of exam ***A periodic table & cover sheet with equations will be attached.***

Metacognition & Reasoning Can I visualize what’s happening? What are the principles and tools I can use to solve this? Why can I use these? Is the answer reasonable?

Some Tools & Principles particles (atoms or molecules) × 1 mole molar mass g × 6.022× 10 23 1 mole grams moles × 1 mole 6.022× 10 23 × molar mass g 1 mole Use PV=nRT PV=nRT (Solve for n) Gas properties Other tools: Dalton’s Law of Partial Pressures Empirical & Molecular Formula Naming

Clicker#1 A closed tank consists of a mixture of 4.00 grams of helium and 160. grams of an unknown monatomic gas. The partial pressure of the unknown gas is four times the partial pressure of helium. Identify the gas. a) Kr b) Tb c) Ar d) Br e) F

Practice Question #2 Problem #118 Part a A 2.50-L flexible balloon at 1.00 atm and -48C is filled with 2.71 g of a monatomic gas. Determine the identity of the gas.

Clicker #2 Problem #118 Part b Determine what will happen when 10.0 g of oxygen gas is added to the balloon. Compare the balloon before the gas has been added to after the gas has been added. *Note: the balloon is a flexible container. Variables that have changed Variables that are constant a) P, V, n T b) V, n T, P c) P, n d) V, T

Clicker #3 Problem #118 Part b Compare the volume of the balloon before the 10.0 g of oxygen gas has been added to the volume after the gas has been added. The volume of the balloon is the same. The volume of the balloon is larger than it was before but less than twice the size. The volume of the balloon is twice as large as it was before. The volume of the balloon is more than twice as large as it was before.

Clicker #4: Naming and Moles Which has the greatest number of ions if equal mole samples of each are dissolved in water? Iron(III) nitrate Sodium fluoride Potassium phosphate Magnesium acetate At least two of the above have the same greatest number of ions.

Clicker #5: Percent Composition & Naming Which has the greatest number of sodium atoms if equal mass samples of each are dissolved in water? Sodium carbonate Sodium chloride

Clicker #6: Ions & Isotopes A certain ion has 27 electrons and 34 neutrons. Which of the following correctly identifies both the ion and its mass number?   Ion Mass Number a) Cu2+ 63 b) Cu2+ 61 c) Co2+ 61 d) Co2+ 59 e) Se2– 61

Problem #7: Gases You are holding two balloons of the same volume. One balloon contains 1.0 g of helium. The other balloon contains neon. Calculate the mass of neon in the balloon.