Suspension Processing of Microporous Metal-Organic Frameworks: A Scalable Route to High-Quality Adsorbents Angelo Kirchon, Gregory S. Day, Yu Fang, Sayan.

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Presentation transcript:

Suspension Processing of Microporous Metal-Organic Frameworks: A Scalable Route to High-Quality Adsorbents Angelo Kirchon, Gregory S. Day, Yu Fang, Sayan Banerjee, Osman K. Ozdemir, Hong-Cai Zhou iScience Volume 5, Pages 30-37 (July 2018) DOI: 10.1016/j.isci.2018.06.009 Copyright © 2018 Terms and Conditions

iScience 2018 5, 30-37DOI: (10.1016/j.isci.2018.06.009) Copyright © 2018 Terms and Conditions

Figure 1 Suspension Processing Methodology Step 1, addition of reaction vessel contents into suspension processing apparatus; step 2, suspension processing; step 3, filtration. iScience 2018 5, 30-37DOI: (10.1016/j.isci.2018.06.009) Copyright © 2018 Terms and Conditions

Figure 2 Suspension-Processed PCN-250 Characterization (A) Powder X-ray diffraction pattern of suspension-processed PCN-250. (B) N2 adsorption isotherm at 77 K suspension-processed PCN-250. (C) BET surface area vs. time of processing for suspension-processed PCN-250. Error bars were determined from three different measurments from three different samples. (D) High-pressure methane uptake for PCN250-20 day compared with commercial PCN-250. iScience 2018 5, 30-37DOI: (10.1016/j.isci.2018.06.009) Copyright © 2018 Terms and Conditions

Figure 3 Scanning Electron Micrographs and Thermal Gravimetric Analysis Curves (A) Scanning electron micrographs of PCN250-6 hr. (B) Scanning electron micrographs of PCN250-20 day. (C) TGA curve for PCN250-6 hr (black) and PCN250-20 day (red). (D) Scanning electron micrographs of HKUST1-6 hr. (E) Scanning electron micrographs of HKUST1-48 hr. (F) TGA curve for HKUST1-6 hr (black) and HKUST1-48 hr (red). (G) Scanning electron micrographs of UiO66-1 hr. (H) Scanning electron micrographs of UiO66-48 hr. (I) TGA curve for UiO66-1 hr (black) and UiO66-48 hr (red). Scale bars 10μm. iScience 2018 5, 30-37DOI: (10.1016/j.isci.2018.06.009) Copyright © 2018 Terms and Conditions

Figure 4 Operational Cost Analysis for Suspension Processing vs. Traditional Solvent Exchange (A) Solvent cost per kg of MOF. (B) Labor cost per kg of MOF. iScience 2018 5, 30-37DOI: (10.1016/j.isci.2018.06.009) Copyright © 2018 Terms and Conditions