KER predictions for Br+ images

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Presentation transcript:

KER predictions for Br+ images Relevant to one- and two- color experiments. Br/Br* Red, green and blue arrows are there to give an idea, but not accurate locations for the formations of the bromine atoms Arrow no.1 is located at expected top of peak Arrow no.2 estimated beginning of peak formation (highest KER possible) Link for excel file (comes later) Updated: 170808

Two color (MOPO & DYE) 66019 cm-1 1 1 1 2 2 2 eV

Two color (MOPO & DYE) 67275 cm-1 1 1 1 2 Br 2 2 eV

Two color (MOPO & DYE) 67275 cm-1 1 It is likely that the blue curve is oriented in the inverse vertical direction (seen below) 1 1 2 2 2 Br* eV

Two color (MOPO & DYE) 68684 cm-1 1 1 1 2 2 2 Br eV

68684 cm-1 Two color (MOPO & DYE) MOPO DYE 1 1 It is likely that the blue curve is oriented in the inverse vertical direction (seen below) 1 2 2 2 eV

Two color (MOPO & DYE) 72977 cm-1 1 1 1 2 2 2 Br eV

72977 cm-1 1 Two color (MOPO & DYE) MOPO DYE 1 It is likely that the blue curve is oriented in the inverse vertical direction (seen below) 1 2 2 2 eV

Two color (MOPO & DYE) 75905 cm-1 1 1 1 2 2 2 Br eV

Two color (MOPO & DYE) 75905 cm-1 1 1 1 2 2 2 Br* eV

1 One color (MOPO) 66019 2

1 One color (MOPO) 68684 2

Two color Br/Br* Color coding for slides 13-15 Red energy values show possible fractional formation seen for top of peaks Blue energy values show possible fractional formation seen for beginning of peaks (seen from the left) Behind every channel is the amount of photons (n hv) needed to form the fragments (not included the amount needed to ionize the fragment). That is different quantity of photons for each fragment/atom in question… Color coding for slides 16-18 Blue text is for formation including CH fragment Green text is for formation including CH2 fragment Red text is for formation including CH3 fragment Slides 13-15 and 16-18 are the same energy numbers, just different purpose of color coding ;)

66019 KERBr cm-1 tot 72977 KERBr cm-1 tot 75905 KERBr cm-1 tot CH2*1 + H+Br (0.463 eV) -23404 3 hv CH*3+2H+Br (0.356 eV) -17998 4 hv CH3 + Br (0.265 eV) -13364 1 hv CH3*2 + Br (0.286 eV) -14468 3 hv CH*2+2H+Br (0.413 eV) -20853 4 hv CH*4+2H+Br (0.357 eV) -18097 4 hv CH*5+H2+Br (0.397 eV) -20095 4 hv CH*4+H2+Br (0.327 eV) -16591 3 hv 67275 CH*3+H2+Br (0.354 eV) -17956 3 hv CH2*5 + H+Br (0.317 eV) -16090 4 hv CH*2+H2+Br (0.243 eV) -12258 3 hv CH*2+H2+Br (0.412 eV) -20811 3 hv CH2*4 + H+Br (0.332 eV) -16765 4 hv CH3*2 + Br (0.324 eV) -16352 3 hv CH2*2 + H+Br (0.349 eV) -17700 4 hv CH2*3 + H+Br (0.337 eV) -17048 4 hv 68684 CH3*4 + Br (0.357 eV) -18072 3 hv CH3*6 + Br (0.332 eV) -16761 3 hv CH*2+2H+Br (0.243 eV) -12267 4 hv CH3*3 + Br (0.362 eV) -18341 3 hv CH3*5 + Br (0.385 eV) -19416 3 hv CH*2+H2+Br (0.284 eV) -14372 3 hv CH3*2 + Br (0.493 eV) -24905 3 hv CH3*2 + Br (0.365 eV) -18466 3 hv

66019 KERBr cm-1 tot 67275 KERBr cm-1 tot 68684 KERBr cm-1 tot CH3 + Br (0.820 eV) -41431 2 hv CH*3+H2+Br (0.851 eV) -43041 4 hv CH3*1 + Br (0.637 eV) -32199 3 hv CH*3+H2+Br (0.803 eV) -40529 4 hv CH3*6 + Br (0.740 eV) -37454 4 hv 72977 CH*2+H2+Br (0.859 eV) -43384 4 hv CH3*5 + Br (0.793 eV) -40109 4 hv CH+2H+Br (0.871 eV) -44042 4 hv CH3*4 + Br (0.804 eV) -40645 4 hv CH3*4 + Br (0.854 eV) -43157 4 hv CH+H2+Br (0.869 eV) -44000 3 hv CH3*3 + Br (0.809 eV) -40914 4 hv CH3*3 + Br (0.859 eV) -43426 4 hv CH2 + H+Br (0.897 eV) -45338 3 hv CH3*2 + Br (0.939 eV) -47478 4 hv 68684 CH3 + Br (0.957 eV) -48389 2 hv 67275 CH+2H+Br (0.701 eV) -35456 4 hv CH*1+2H+Br (0.756 eV) -38198 4 hv CH+H2+Br (0.701 eV) -35447 3 hv CH+H2+Br (0.744 eV) -37561 3 hv CH*4+H2+Br (0.964 eV) -48688 4 hv CH2 + H+Br (0.728 eV) -36785 3 hv CH2 + H+Br (0.769 eV) -38898 3 hv CH*1+H2+Br (0.755 eV) -38156 3 hv CH3 + Br (0.844 eV) -42687 2 hv CH*4+H2+Br (0.793 eV) -40102 4 hv CH3*6 + Br (0.967 eV) -48858 4 hv CH*4+H2+Br (0.737 eV) -37284 4 hv CH3*6 + Br (0.796 eV) -40272 4 hv CH3*1 + Br (0.764 eV) -38638 3 hv CH3 + Br ??????????????????

75905 KERBr cm-1 tot CH+2H+Br -49898 4 hv CH+H2+Br -48392 3 hv (0.988 eV) -49898 4 hv CH+H2+Br (0.957 eV) -48392 3 hv CH2 + H+Br (0.985 eV) -49730 3 hv CH*1+2H+Br (0.871 eV) -44054 4 hv CH*1+H2+Br (0.843 eV) -42548 3 hv CH3*1 + Br (0.852 eV) -43030 3 hv CH3 + Br ?????????????????? 2hv

66019 KERBr cm-1 tot 72977 KERBr cm-1 tot 75905 KERBr cm-1 tot CH2*1 + H+Br (0.463 eV) -23404 3 hv CH*3+2H+Br (0.356 eV) -17998 4 hv CH3 + Br (0.265 eV) -13364 1 hv CH3*2 + Br (0.286 eV) -14468 3 hv CH*2+2H+Br (0.413 eV) -20853 4 hv CH*4+2H+Br (0.357 eV) -18097 4 hv CH*5+H2+Br (0.397 eV) -20095 4 hv CH*4+H2+Br (0.327 eV) -16591 3 hv 67275 CH*3+H2+Br (0.354 eV) -17956 3 hv CH2*5 + H+Br (0.317 eV) -16090 4 hv CH*2+H2+Br (0.243 eV) -12258 3 hv CH*2+H2+Br (0.412 eV) -20811 3 hv CH2*4 + H+Br (0.332 eV) -16765 4 hv CH3*2 + Br (0.324 eV) -16352 3 hv CH2*2 + H+Br (0.349 eV) -17700 4 hv CH2*3 + H+Br (0.337 eV) -17048 4 hv 68684 CH3*4 + Br (0.357 eV) -18072 3 hv CH3*6 + Br (0.332 eV) -16761 3 hv CH*2+2H+Br (0.243 eV) -12267 4 hv CH3*3 + Br (0.362 eV) -18341 3 hv CH3*5 + Br (0.385 eV) -19416 3 hv CH*2+H2+Br (0.284 eV) -14372 3 hv CH3*2 + Br (0.493 eV) -24905 3 hv CH3*2 + Br (0.365 eV) -18466 3 hv

66019 KERBr cm-1 tot 67275 KERBr cm-1 tot 68684 KERBr cm-1 tot CH3 + Br CH3 + Br (0.820 eV) -41431 -41431 2 hv CH*3+H2+Br (0.851 eV) -43041 4 hv CH3*1 + Br (0.637 eV) -32199 3 hv CH*3+H2+Br (0.803 eV) -40529 4 hv CH3*6 + Br CH3*6 + Br (0.740 eV) -37454 -37454 4 hv 72977 CH*2+H2+Br (0.859 eV) -43384 4 hv CH3*5 + Br CH3*5 + Br (0.793 eV) -40109 -40109 4 hv CH+2H+Br (0.871 eV) -44042 4 hv CH3*4 + Br CH3*4 + Br (0.804 eV) -40645 -40645 4 hv CH3*4 + Br CH3*4 + Br (0.854 eV) -43157 -43157 4 hv CH+H2+Br (0.869 eV) -44000 3 hv CH3*3 + Br CH3*3 + Br (0.809 eV) -40914 -40914 4 hv CH3*3 + Br CH3*3 + Br (0.859 eV) -43426 -43426 4 hv CH2 + H+Br (0.897 eV) -45338 3 hv CH3*2 + Br CH3*2 + Br (0.939 eV) -47478 -47478 4 hv 68684 CH3 + Br CH3 + Br (0.957 eV) -48389 -48389 2 hv 67275 CH+2H+Br (0.701 eV) -35456 4 hv CH*1+2H+Br (0.756 eV) -38198 4 hv CH+H2+Br (0.701 eV) -35447 3 hv CH+H2+Br (0.744 eV) -37561 3 hv CH*4+H2+Br (0.964 eV) -48688 4 hv CH2 + H+Br (0.728 eV) -36785 3 hv CH2 + H+Br (0.769 eV) -38898 3 hv CH*1+H2+Br (0.755 eV) -38156 3 hv CH3 + Br CH3 + Br (0.844 eV) -42687 -42687 2 hv CH*4+H2+Br (0.793 eV) -40102 4 hv CH3*6 + Br (0.967 eV) -48858 4 hv CH*4+H2+Br (0.737 eV) -37284 4 hv CH3*6 + Br CH3*6 + Br 4 hv (0.796 eV) -40272 -40272 CH3*1 + Br (0.764 eV) -38638 3 hv CH3 + Br ??????????????????

75905 KERBr cm-1 tot CH+2H+Br -49898 4 hv CH+H2+Br -48392 3 hv (0.988 eV) -49898 4 hv CH+H2+Br (0.957 eV) -48392 3 hv CH2 + H+Br (0.985 eV) -49730 3 hv CH*1+2H+Br (0.871 eV) -44054 4 hv CH*1+H2+Br (0.843 eV) -42548 3 hv CH3*1 + Br (0.852 eV) -43030 3 hv CH3 + Br ?????????????????? 2hv

Comparing the one color (MOPO or Dye) and two color (MOPO and Dye) for Br/Br* Red KER is the MOPO one color measurements Green KER is the Dye laser one color measurements Blue KER is the two color (both MOPO and dye) “KER are not to scale”

One color Br - dye One color Br - MOPO Two color Br 68684 cm-1

One color Br - dye One color Br - MOPO Two color Br 72977 cm-1

66019 Process 1 13340.43 1.65411 0.26395 CH3 Dy Dy 33010 Process 2 19026.57 2.35915 0.37646 CH3+ Process 3 8845 1.09677 0.17502 Mo Dy Process 4 14532 1.80181 0.28752

67275 Process 1 13340 1.65411 0.26395 CH3 Dy Dy 33638 Process 2 19027 2.35915 0.37646 CH3+ Process 3 9473 1.17464 0.18744 Mo Dy Process 4 15160 1.87967 0.29995

72977 Process 1 13340 1.65411 0.26395 CH3 Dy Dy 36489 Process 2 19027 2.35915 0.37646 CH3+ Process 3 12324 1.52814 0.24385 Mo Dy Process 4 18011 2.23318 0.35636