Chemistry 25.2.

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Presentation transcript:

Chemistry 25.2

Nuclear Transformations 25.2 Nuclear Transformations Radon-222 is a radioactive isotope that is present naturally in the soil in some areas. It has a constant rate of decay. You will learn about decay rates of radioactive substances.

Nuclear Stability and Decay 25.2 Nuclear Stability and Decay Nuclear Stability and Decay What determines the type of decay a radioisotope undergoes?

Nuclear Stability and Decay 25.2 Nuclear Stability and Decay The neutron-to-proton ratio determines the type of decay that occurs. A positron is a particle with the mass of an electron but a positive charge. During positron emission, a proton changes to a neutron.

Nuclear Stability and Decay 25.2 Nuclear Stability and Decay The nuclear force is an attractive force that acts between all nuclear particles that are extremely close together, such as protons and neutrons in a nucleus At these short distances, the nuclear force dominates over electromagnetic repulsions and hold the nucleus together.

Nuclear Stability and Decay 25.2 Nuclear Stability and Decay More than 1,500 different nuclei are known. Of those, only 264 are stable and do not decay or change with time. These nuclei are in a region called the band of stability.

Nuclear Stability and Decay 25.2 Nuclear Stability and Decay A neutron-versus-proton plot of all stable nuclei forms a pattern called the band of stability (shown in red). INTERPRETING GRAPHS a. Identify What do the dots on the graph represent? b. Apply Concepts What is the approximate ratio of neutrons to protons for neodymium, whose atomic number is 60? c. Describe How does the neutron-to-proton ratio change as the number of protons increases?

Nuclear Stability and Decay 25.2 Nuclear Stability and Decay

25.2 Half-Life Half-Life How much of a sample of a radioisotope remains after each half-life?

25.2 Half-Life What is half-life? A half-life (t1/2) is the time required for one-half of the nuclei of a radioisotope sample to decay to products. After each half-life, half of the existing radioactive atoms have decayed into atoms of a new element.

25.2 Half-Life This decay curve shows that during each half-life, half of the radioactive atoms decay exponentially into atoms of another element. INTERPRETING GRAPHS a. Identify What percent of the atoms remains after 1 half-life? b. Describe What percent of the atoms remains after two half-lives? c. Apply Concepts Approximately how many half-lives does it take for 12.5% of the radioisotope to remain?

25.2 Half-Life

25.2 Stable Isotope Half-Life Uranium-238 decays through a complex series of radioactive intermediates, including radon (Rn) gas. Interpreting Diagrams What is the stable end product of this series? Stable Isotope

25.2 Half-Life The ratio of Carbon-14 to stable carbon in the remains of an organism changes in a predictable way that enables the archaeologist to obtain an estimate of its age. This archaeologist is digging for artifacts. The age of an artifact can often be determined from its measured carbon-14 content.

25.1

25.1

25.1

25.1

for Sample Problem 25.1 Problem Solving 25.7 Solve Problem 7 with the help of an interactive guided tutorial.

Transmutation Reactions 25.2 Transmutation Reactions Transmutation Reactions What are two ways that transmutation can occur?

Transmutation Reactions 25.2 Transmutation Reactions What is transmutation? The conversion of an atom of one element to an atom of another element is called transmutation. Transmutation can occur by radioactive decay. Transmutation can also occur when particles bombard the nucleus of an atom.

Transmutation Reactions 25.2 Transmutation Reactions The first artificial transmutation reaction involved bombarding nitrogen gas with alpha particles. The first artificial transmutation reaction involved bombarding nitrogen gas with alpha particles, as illustrated here. Interpreting Diagrams What particles were formed?

Transmutation Reactions 25.2 Transmutation Reactions The elements in the periodic table with atomic numbers above 92, the atomic number of uranium, are called the transuranium elements. All transuranium elements undergo transmutation. None of the transuranium elements occur in nature, and all of them are radioactive.

Transmutation Reactions 25.2 Transmutation Reactions Transuranium elements are synthesized in nuclear reactors and nuclear accelerators. Fermilab is a major accelerator center located in Batavia, Illinois. The main accelerator is a ring that has a radius of 1.0 km.

25.2 Section Quiz. 25.2.

25.2 Section Quiz. 1. During nuclear decay, if the atomic number decreases by one but the mass number is unchanged, the radiation emitted is a positron. an alpha particle. a neutron. a proton.

25.2 Section Quiz. 2. When potassium-40 (atomic number 19) decays into calcium-40 (atomic number 20), the process can be described as positron emission. alpha emission. beta emission. electron capture.

25.2 Section Quiz. 3. If there were 128 grams of radioactive material initially, what mass remains after four half-lives? 4 grams 32 grams 16 grams 8 grams

25.2 Section Quiz. 4. When transmutation occurs, the ________ always changes. number of electrons mass number atomic number number of neutrons

25.2 Section Quiz 5. Transmutation occurs by radioactive decay and also by extreme heating. chemical reaction. high intensity electrical discharge. particle bombardment of the nucleus.

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