Volume 1, Issue 3, Pages (November 2017)

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Volume 1, Issue 3, Pages 431-442 (November 2017) Vapor-Deposited Perovskites: The Route to High-Performance Solar Cell Production?  Jorge Ávila, Cristina Momblona, Pablo P. Boix, Michele Sessolo, Henk J. Bolink  Joule  Volume 1, Issue 3, Pages 431-442 (November 2017) DOI: 10.1016/j.joule.2017.07.014 Copyright © 2017 Elsevier Inc. Terms and Conditions

Joule 2017 1, 431-442DOI: (10.1016/j.joule.2017.07.014) Copyright © 2017 Elsevier Inc. Terms and Conditions

Figure 1 Methylammonium Salts Thermal Decomposition and Substrate Growing Dependence (A and B) FTIR spectra of the decomposition products for (A) MACl and (B) MAI. Extracted with permission from Williams et al.32 (C) Overview of the UPS data taken on four different substrates (from left to right: PEIE, ITO, PEDOT:PSS, and MoO3); onto these, the perovskite MAPbI3 was deposited at increasing thickness (d, in nm). Reprinted with permission from Olthof and Meerholz.40 Joule 2017 1, 431-442DOI: (10.1016/j.joule.2017.07.014) Copyright © 2017 Elsevier Inc. Terms and Conditions

Figure 2 Morphology of Methylammonium Lead Iodide for Different Deposition Techniques (A–F) Scanning electron microscopy images of MAPbI3 films deposited through different methods and on different substrates. Scale bar, 500 nm. Reproduced from and modified with permission from Momblona et al.26 (A), Olthof and Meerholz40 (B), Hsiao et al.47 (C), Li et al.48 (D), Yin et al.49 (E), and Xu et al.50 (F). Joule 2017 1, 431-442DOI: (10.1016/j.joule.2017.07.014) Copyright © 2017 Elsevier Inc. Terms and Conditions

Figure 3 Evolution of Perovskite Solar Cell Power Conversion Efficiencies Comparison between the evolutions of the best research-cell efficiencies obtained by solution-processing (from nrel.gov) and literature values of vapor-deposited perovskite solar cells. Joule 2017 1, 431-442DOI: (10.1016/j.joule.2017.07.014) Copyright © 2017 Elsevier Inc. Terms and Conditions

Figure 4 Monolithic Tandem Solar Cells (A) Device layout and current density versus voltage characteristics under illumination for monolithic perovskite/perovskite tandem solar cells. Reproduced with permission from Forgács et al.83 (B) Schematic drawings of monolithic perovskite/Si tandem device with rear-side texture and the corresponding scanning electron microscopy cross-section images for the front and rear side. Reproduced with permission from Werner et al.85 Joule 2017 1, 431-442DOI: (10.1016/j.joule.2017.07.014) Copyright © 2017 Elsevier Inc. Terms and Conditions