The Discovery of C60 ACS Philadelphia 2016.

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Presentation transcript:

The Discovery of C60 ACS Philadelphia 2016

Rick atop Ap2

Cluster beam TOF mass spectrometer Ion Detector Laser vaporization Cluster Source UV Laser Ionization

Cluster beam source

Harry Kroto 5

Carbon Chain Molecules Found in Interstellar Clouds

Emulating the Stars in the Lab

The Diffuse ISB’s NASA

Origin of the Diffuse Interstellar lines Here I suggest that the lines are caused by the absorption of polyatomic molecules and that the line width is the result of radiationless internal conversion between stable states. Furthermore, I propose that the absorbing species are long chain carbon molecules, Cn, where n may lie in the range 5-15. A. E. Douglas, Nature 269, 130 (1977)

Variations in C60 peak intensity

Buckminster Fuller’s Dome at Expo 67

Smalley’s C60 Paper Model

Kroto’s Stardome Map of the sky on a truncated icosahedron consisting of pentagons as well as hexagons

Buckminsterfullerene

Osawa 1971

Adjacent Pentagon Fullerenes One of 1812 fullerene isomers with 60 carbon atoms

After bucky C60, this C70 structure is the first without adjacent pentagons

Arc Apparatus for Making Fullerenes Krätschmer et al.

The diffuse interstellar bands In the original letter to Nature, we suggested that buckminsterfullerene might be a carrier of the dib’s. After enormous creative effort, John Maier’s group found two clear matches* of C60+. E.K. Campbell, M. Holz, D. Gerlich and J.P. Maier Nature. 523: 322 (2015)

Konarka flexible portable panel