Novel Organic-Inorganic Hybrid Cage Architectures

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Novel Organic-Inorganic Hybrid Cage Architectures Radu F. Semeniuc, Department of Chemistry, Eastern Illinois University The synthesis of Metal-Organic-Rotaxane-Frameworks witnessed an increased interest during the last decade, due to their potential to function as molecular machines. We have successfully synthesized anionic rotaxanes that produced, after coordination to cationic metal-containing centres, neutral rotaxanes. These anionic rotaxanes will enable us to prepare more complex architectures by changing the coordination preferences of the metal and employing (or not) additional ligands