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Nat. Rev. Mater. doi:10.1038/natrevmats.2015.7 Figure 1 Timeline of research into the optoelectronic properties of HOIPs and important discoveries in the development of HOIP solar cells Image b adapted with permission from Kojima, A., Teshima, K., Shirai, Y. and Miyasaka, T. Organometal halide perovskites as visible-light sensitizers for photovoltaic cells. J. Am. Chem. Soc. 131, 6050–6051 (2009). Copyright (2009) American Chemical Society. Image c from Lee, M. M., Teuscher, J., Miyasaka, T., Murakami, T. N. and Snaith, H. J. Efficient hybrid solar cells based on meso-superstructured organometal halide perovskites. Science 338, 643–647 (2012). Reprinted with permission from AAAS. Image d from Yang, W. S. et al. High-performance photovoltaic perovskite layers fabricated through intramolecular exchange. Science 348, 1234–1237 (2015). Reprinted with permission from AAAS Brenner. et al. (2016) Hybrid organic–inorganic perovskites: low-cost semiconductors with intriguing charge-transport properties Nat. Rev. Mater. doi:10.1038/natrevmats.2015.7