Synthesis and Characterization of Novel Donor/Acceptor

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Synthesis and Characterization of Novel Donor/Acceptor Molecules Based on Propellanes: A Probe of Nonclassical Conjugation Frankie Ann McCormick, Department of Chemistry, Northern Michigan University Study provides the first experimental evidence for charge transfer between donor and acceptor groups linked by 1,3-diethynylpropellanes. UV absorption and fluorescence spectra indicate significant interaction through the propellane spacer—the molecules exhibit substantial charge transfer as seen from the bathochromic shift of the emission with increasing solvent polarity. Potential applications of these molecules include optics, molecular electronics, and energy transfer. Figure 1. UV Absorption Spectra of 2 in Cyclohexane. Figure 2. Normalized emission spectra of 1 in solvents of different polarity. (Excitation at 270 nm)