Problem Set – Litterature

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Presentation transcript:

Problem Set – Litterature A presentation by Guillaume Pelletier on October 27th 2009

Question #1: [1,4]-Conjugated Addition of an Organo-Rhodium speicies. (a) Wuitschik, G.; Rogers-Evans, M.; Müller, K.; Fisher, H.; Wagner, B.; Schuler, F.; Polonchuk, L.; Carreira, E. M. Angew. Chem. Int. Ed. 2006, 45, 7736-7739. (b) Fagnou, K.; Lautens, M. Chem. Rev. 2003, 103, 169-193.

Question #1: [1,4]-Conjugated Addition of an Organo-Rhodium speicies. (a) Wuitschik, G.; Rogers-Evans, M.; Müller, K.; Fisher, H.; Wagner, B.; Schuler, F.; Polonchuk, L.; Carreira, E. M. Angew. Chem. Int. Ed. 2006, 45, 7736-7739. (b) Fagnou, K.; Lautens, M. Chem. Rev. 2003, 103, 169-193.

Question #2: Formation of an [1,2]-trans-Aminoalcohol from an Oxetane. Bach, T.; Schröder, J. J. Org. Chem. 1999, 64, 1265-1273.

Question #2: Formation of an [1,2]-trans-Aminoalcohol from an Oxetane. Bach, T.; Schröder, J. J. Org. Chem. 1999, 64, 1265-1273.

Question #3: Oxetane by fragmentation (a) Marshall, J. A.; Arrington, J. P. J. Org. Chem. 1971, 36, 214-215. (b) Waters, J. A.; Witkop, B. J. Org. Chem. J. Org. Chem. 1969, 34, 3774.

Question #3: Oxetane by fragmentation Marshall, J. A.; Arrington, J. P. J. Org. Chem. 1971, 36, 214-215. (b) Waters, J. A.; Witkop, B. J. Org. Chem. J. Org. Chem. 1969, 34, 3774. (c) Moran, J.; Dornan, P.; Beauchemin, A. M. Org. Lett. 2007, 9, 3893-3896.

Question #3: Oxetane by fragmentation Marshall, J. A.; Arrington, J. P. J. Org. Chem. 1971, 36, 214-215. (b) Waters, J. A.; Witkop, B. J. Org. Chem. J. Org. Chem. 1969, 34, 3774. (c) Moran, J.; Dornan, P.; Beauchemin, A. M. Org. Lett. 2007, 9, 3893-3896.

Question #3: Oxetane by fragmentation Marshall, J. A.; Arrington, J. P. J. Org. Chem. 1971, 36, 214-215. (b) Waters, J. A.; Witkop, B. J. Org. Chem. J. Org. Chem. 1969, 34, 3774. (c) Moran, J.; Dornan, P.; Beauchemin, A. M. Org. Lett. 2007, 9, 3893-3896.

Question #4: Allylic strain Bach, T.; Jödicke, K.; Kather, K.; Frölich, R. J. Am. Chem. Soc. 1997, 119, 2437-2445.

Question #4: Allylic strain Bach, T.; Jödicke, K.; Kather, K.; Frölich, R. J. Am. Chem. Soc. 1997, 119, 2437-2445.

Question #5 : « Norrish type 2-like » fragmentation Booker-Milburn, K. I.; Baker, J. R.; Bruce, I. Org. Lett. 2004, 6, 1481-1484.

Question #5 : « Norrish type 2-like » fragmentation Booker-Milburn, K. I.; Baker, J. R.; Bruce, I. Org. Lett. 2004, 6, 1481-1484.