Standard Temperature and Pressure

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Presentation transcript:

Standard Temperature and Pressure Normally volumes are reported at standard conditions. It is normally abbreviated STP (standard temperature and pressure) Standard temperature is 273 K or 0o C Standard pressure is 101 kPa, or 760 torr, or 1.00 atm.

Avogadro’s Law Avogadro discovered that the size or type of molecule or atom of a gas had no effect on the volume of that gas. His law states… ~equal volumes of different gases at the same temperature and pressure contain the same number of molecules. 1.00 mol of any gas at STP will occupy 22.4 L

To convert… What volume will .67 mol of a gas occupy at STP? .67mol 22.4 L (at STP) 1 mol = 15.008 15 L at STP What volume will .67 mol of a gas occupy at 740 torr and 295 K?

Add this into combined gas law Vi Pi / Ti = Vf Pf / Tf What volume will .67 mol of a gas occupy at 740 torr and 295 K? 15.008 L (760 torr)/273 K = V (740 torr)/295K V = 17 L

More What volume will .83 mol of a gas occupy at .82 atm and 264 K? .83 mol 22.4 L (at STP) 1 mol = 18.592 L at STP 18.592 L (1.00 atm)/273 K = V (.82 atm)/264 K V = 22 L

A problem 126 mL of nitrogen at 113 kPa and 39o C will occupy what volume at STP? VP/T = VP/T 126 mL (113 kPa)/312K = V 101 kPa/273K V = 123 mL

Homework 3.45 mol of acetylene will occupy what volume at 102 kPa and 315 K?