Aamod V. Desai, Arkendu Roy, Partha Samanta, Biplab Manna, Sujit K

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Base-Resistant Ionic Metal-Organic Framework as a Porous Ion-Exchange Sorbent Aamod V. Desai, Arkendu Roy, Partha Samanta, Biplab Manna, Sujit K. Ghosh iScience Volume 3, Pages 21-30 (May 2018) DOI: 10.1016/j.isci.2018.04.004 Copyright © 2018 The Authors Terms and Conditions

iScience 2018 3, 21-30DOI: (10.1016/j.isci.2018.04.004) Copyright © 2018 The Authors Terms and Conditions

Figure 1 Structural Features and Characterization of IPM-MOF-201 (A) Coordination environment in IPM-MOF-201. (B) Perspective view of packing in IPM-MOF-201 showing porous channels. (Hydrogen atoms and disordered anions have been omitted for clarity. Color code: Ni, green; C, gray, N, blue). See also Figure S1–S19 and Table S2. iScience 2018 3, 21-30DOI: (10.1016/j.isci.2018.04.004) Copyright © 2018 The Authors Terms and Conditions

Figure 2 Stability Studies in IPM-MOF-201 (A) Water adsorption isotherm for IPM-MOF-201 at 298 K (closed and open symbols denote adsorption and desorption, respectively). (B) PXRD patterns of pH = 4 (green) and pH = 14 (red) dipped phases, relative to the as-synthesized phase (blue) and simulated pattern (gray). (C) CO2 adsorption profiles (273 K) of base-treated phases of IPM-MOF-201. (D) Photographs of different phases recorded by optical microscope and the corresponding FESEM images after 24 hr. See also Figure S20–S38 and Tables S1 and S3. iScience 2018 3, 21-30DOI: (10.1016/j.isci.2018.04.004) Copyright © 2018 The Authors Terms and Conditions

Figure 3 Dye Capture Studies by IPM-MOF-201 Summary showing photographs of all the phases of compound IPM-MOF-201 and the dye-exchange phases under different conditions. The corresponding SEM images of each phase are shown alongside. See also Figure S39–S65. iScience 2018 3, 21-30DOI: (10.1016/j.isci.2018.04.004) Copyright © 2018 The Authors Terms and Conditions