Fig. 4 2D-IR spectroscopy on LO/Zn under wet and dry conditions.

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Presentation transcript:

Fig. 4 2D-IR spectroscopy on LO/Zn under wet and dry conditions. 2D-IR spectroscopy on LO/Zn under wet and dry conditions. (A) Linear IR spectrum of LO/Zn ionomer soaked in water. (B) 2D-IR spectrum of wet LO/Zn with perpendicular polarization of pump and probe pulses (delay, 1 ps; contour intervals are at 0.17 mOD). (C) Polarization difference spectrum of wet LO/Zn showing broad cross peaks. (D) Linear IR spectrum of LO/Zn dried by heating to 150°C for 30 min. (E) Perpendicular 2D-IR spectrum of dry LO/Zn (delay, 1.5 ps; contour intervals are at 0.16 mOD). (F) Polarization difference spectrum of dry LO/Zn. (G) Cross section of the 2D spectrum shown in (E) and (F) at a pump frequency of 1532 cm−1, showing a coupling pattern that is highly similar to Fig. 2D. Joen. J. Hermans et al. Sci Adv 2019;5:eaaw3592 Copyright © 2019 The Authors, some rights reserved; exclusive licensee American Association for the Advancement of Science. No claim to original U.S. Government Works. Distributed under a Creative Commons Attribution NonCommercial License 4.0 (CC BY-NC).