Photocapacitance measurements on GaP alloys for high efficiency solar cells Dan Hampton and Tim Gfroerer , Davidson College, Davidson, NC Mark Wanlass, National Renewable Energy Lab, Golden, CO Acknowledgements Davidson Research Initiative American Chemical Society Petroleum Research Fund Jeff Carapella for growing and processing test structures
Solar Cell Operation
Conduction Band Conduction Band Valence Band Valence Band Valence Band E=hc/λ Energy + Valence Band Valence Band Valence Band Valence Band
Conduction Band E=hc/λ Energy + Valence Band Valence Band
Conduction Band Conduction Band Conduction Band Conduction Band Energy Electron-Hole Pair + + Valence Band Valence Band
Conduction Band Conduction Band Conduction Band Conduction Band Band Edge Energy + + Valence Band Valence Band
Conduction Band Conduction Band Conduction Band Conduction Band Heat Conduction Band Conduction Band Conduction Band Conduction Band Band Edge Energy Ephoton – Band Gap Energy = Energy Lost + + Valence Band Valence Band
Defects
Conduction Band Conduction Band Valence Band Valence Band Valence Band Defect Levels Increasing Energy Trap Depth + + + + + + Valence Band Valence Band Valence Band Valence Band Hole
Conduction Band Conduction Band Valence Band Valence Band Valence Band + Defect Levels Defect Levels Defect Levels + Increasing Energy Trap Depth Capture + + + + + Valence Band Valence Band Valence Band Hole
Conduction Band Conduction Band Valence Band Valence Band Valence Band Defect Levels Defect Levels Defect Levels + Increasing Energy Escape Trap Depth + + + + + + Valence Band Valence Band Valence Band Hole
1 mm Picture of Device
N+ P - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - Photocapacitance - - - - + + - - - - + - - - + - - - + N+ - P - - + - - + - - - - + - - + - - - - - + - + Depletion with bias
Depletion without bias Photocapacitance - - - - + + - - - - + - - - + - - - + N+ - P - - + - - + - - - - + + - - - - - - - + - + Depletion without bias
Depletion without bias Depletion Layer - - - - + - + - - - + - - - - + - + - - N+ - P - - + - - - - + - + - + - + - - - - - - + Depletion without bias
Depletion without bias Depletion Layer T = 77 K - - - - + - + - - - + - - - - + - + - - N+ - P - - + - - + - - - - + + - + - - - - - - + Depletion without bias
Depletion without bias Depletion Layer T = 77 K - - - - + + - - - - + - - - + - - - + N+ - P - - + - - + - - - - + - + - - - - - - + - + Depletion without bias
Conclusions Optical threshold escape energies are higher than thermal threshold energies → Configuration Dependent Traps GaAsP has a very large trap density, comparable to the density of dopants. This suggests zinc is contributing to the formation of the traps.