Hydration Mechanism Section 9.4.

Slides:



Advertisements
Similar presentations
Chapter 6 Chemical Equilibrium. Material Equilibrium (a) Chemical equilibrium, which is equilibrium with respect to conversion of one set of chemical.
Advertisements

Organic Chemistry Second Edition Chapter 12 David Klein Synthesis
1 Chapter 12 Unsaturated Hydrocarbons 12.3 Addition Reactions.
Addition Reactions Chapter 13 Unsaturated Hydrocarbons.
Higher Chemistry Unit 2(c) Uses of addition reactions in industry.
What makes the carbonyl carbon electrophilic? 1.RESONANCE: What would the resonance hybrid look like? 2.INDUCTION: The carbonyl carbon is bonded to a very.
Chemical Equilibrium Green/Damji – Chapter 7.2 Chang - Chapter 14 Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or display.
Organic Chemistry Second Edition Chapter 3 David Klein Acids and Bases
Chemistry: An Introduction to General, Organic, and Biological Chemistry, Eleventh Edition Copyright © 2012 by Pearson Education, Inc. Chapter 11 Unsaturated.
General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 1 Chapter 9 Chemical Equilibrium 9.5 Changing Equilibrium Conditions:
Alkene Reactions.
Acid-Catalyzed Hydration of Alkenes
Addition Reactions and Alkenes
Addition of H 2 O across a Double Bond. Addition of H 2 O across a double bond Occurs in three different ways: Acid-Catalyzed Hydration Oxymercuration.
9.7 Catalytic Hydrogenation The addition of H 2 across a C=C double bond If a chirality center is formed, syn addition is observed Draw the stereoisomers.
UNIT 10 COLLISION THEORY, RATE OF REACTION, LE CHATELIER PRINCIPLE.
9.4 Hydration The components of water (-H and –OH) are added across a C=C double bond The acid catalyst is often shown over the arrow, because it is regenerated.
Klein, Organic Chemistry 2e
10.1 Alkynes Alkynes are molecules that incorporate a C  C triple bond Copyright © 2015 John Wiley & Sons, Inc. All rights reserved Klein, Organic.
Copyright © 2015 John Wiley & Sons, Inc. All rights reserved. Chapter 6 Chemical Reactivity and Mechanisms Organic Chemistry Second Edition David Klein.
Copyright © 2015 John Wiley & Sons, Inc. All rights reserved. Chapter 2 Molecular Representations Organic Chemistry Second Edition David Klein.
19.1 Introduction to Electrophilic Aromatic Substitution
Organic Chemistry Second Edition Chapter 13 David Klein
Organic Chemistry Second Edition Chapter 11 David Klein
7.6 SN1 Complete Mechanisms
8.1 Introduction to Elimination
Goals for the Day… Addition Reactions of Alkenes & Alkynes.
Chemical Reactivity and Mechanisms
22.1 Introduction Alpha Carbon Chemistry: Enols and Enolates
10.4 Preparation of Alkynes
9.5 Oxymercuration-Demercuration
3.4 Qualifying Acidity Qualitative analysis – compare structural stability to determine which is a stronger acid Formal charge can affect stability The.
21.8 Preparation and Reaction of Acid Chlorides
Aromatic Substitution Reactions
Aromatic Substitution Reactions
Klein, Organic Chemistry 2e
Addition Reactions and Alkenes
Carboxylic Acids and Their Derivatives
3.4 Qualifying Acidity Qualitative analysis – compare structural stability to determine which is a stronger acid Formal charge can affect stability The.
Organic Chemistry Second Edition Chapter 10 David Klein Alkynes
1.6 Atomic Orbitals General Chemistry review
Organic Chemistry Third Edition Chapter 9 David Klein Alkynes
Addition Reactions and Alkenes
Alpha Carbon Chemistry: Enols and Enolates
Organic Chemistry Second Edition Chapter 7 David Klein
Organic Chemistry Second Edition Chapter 24 David Klein Carbohydrates
Copyright © 2015 John Wiley & Sons, Inc. All rights reserved.
Organic Chemistry Second Edition Chapter 7 David Klein
Organic Chemistry Second Edition Chapter 24 David Klein Carbohydrates
15.11 Acquiring a 13C NMR Spectrum
Carboxylic Acids and Their Derivatives
Copyright © 2014 John Wiley & Sons, Inc. All rights reserved.
Meso Compounds Section 5.6.
Fischer Projections Section 5.7.
Solomons • Fryhle • Snyder
Page 535 Advanced Engineering Mathematics by Erwin Kreyszig
Solomons • Fryhle • Snyder
Klein, Organic Chemistry 2e
Page 46a Continued Advanced Engineering Mathematics by Erwin Kreyszig
Aromatic Substitution Reactions
Copyright © 2014 John Wiley & Sons, Inc. All rights reserved. Chapter 20 Managing the Multinational Financial System Tenth Edition Alan C. Shapiro Multinational.
Copyright © 2014 John Wiley & Sons, Inc. All rights reserved. Chapter 19 Current Asset Management and Short-Term Financing Tenth Edition Alan C. Shapiro.
Partial Differential Equations
Factors Affecting CB Stability: IO
Hydrohalogenation Section 9.3.
Introduction to Acid/Base Chemistry
Factors Affecting CB Stability: AR
Introduction to Alkene Addition Reactions
Choosing the reagents for a substitution reaction
Regioselectivity of E2 reactions
Presentation transcript:

Hydration Mechanism Section 9.4

9.4 Hydration The components of water (-H and –OH) are added across a C=C double bond The acid catalyst is often shown over the arrow, because it is regenerated rather than being a reactant Copyright © 2015 John Wiley & Sons, Inc. All rights reserved. Klein, Organic Chemistry 2e

9.4 Hydration Mechanism Why does the hydrogen add to this carbon of the alkene? Mechanism continues on next slide Copyright © 2015 John Wiley & Sons, Inc. All rights reserved. Klein, Organic Chemistry 2e

9.4 Hydration Mechanism Could a stronger base help promote the last step? Practice with conceptual checkpoint 9.10 Copyright © 2015 John Wiley & Sons, Inc. All rights reserved. Klein, Organic Chemistry 2e

9.4 Hydration Thermodynamics How could Le Châtelier’s principle be used to shift the equilibrium to the right or left? Practice with conceptual checkpoint 9.11 Copyright © 2015 John Wiley & Sons, Inc. All rights reserved. Klein, Organic Chemistry 2e