Fig. 1 Reaction investigation using single-molecule charge transport measurement and simultaneous NMR characterization. Reaction investigation using single-molecule.

Slides:

Advertisements

Similar presentations

Fig. 3 The electrical contact of direct-printed and reconfigured liquid metals. The electrical contact of direct-printed and reconfigured liquid metals.

Advertisements

Fig. 2 Global production, use, and fate of polymer resins, synthetic fibers, and additives (1950 to 2015; in million metric tons). Global production, use,

Fig. 2 CFD results. CFD results. Results of CFD simulations in horizontal (left column) and vertical (right column) cross-sections. All models oriented.

Fig. 3 Vibrational spectra of human bones from the Copper Age (Scoglietto cave, Italy). Vibrational spectra of human bones from the Copper Age (Scoglietto.

Vibrational spectra of medieval human bones (Leopoli-Cencelle, Italy)

Fig. 2 Reaction kinetics in single-molecule junctions with OEEFs and in NMR tube. Reaction kinetics in single-molecule junctions with OEEFs and in NMR.

Fig. 5 Thermal conductivity of n-type ZrCoBi-based half-Heuslers.

Fig. 1 Map of water stress and shale plays.

Fig. 1 Examples of experimental stimuli and behavioral performance.

Fig. 1 NP-free Ch-CNC droplets.

Fig. 3 Electron PSD in various regions.

Fig. 2 Some examples of weekly forecasts (the number of the forecasts are reported on Table 1). Some examples of weekly forecasts (the number of the forecasts.

Fig. 4 Resynthesized complex boronic acid derivatives based on different scaffolds on a millimole scale and corresponding yields. Resynthesized complex.

HT Suzuki reaction of boronic acids using the building block approach

HT synthesis of boronic acids using the building block approach

Fig. 6 Comparison of properties of water models.

Fig. 1 Mean and median RCR (Relative Citation Ratio) of Roadmap Epigenomics Program research articles for each year. Mean and median RCR (Relative Citation.

Fig. 2 Influence of the Roadmap Epigenomics Program on the field of epigenomics research. Influence of the Roadmap Epigenomics Program on the field of.

Fig. 2 Reference-fixing experiment, results.

Fig. 3 Glucose- and structure-dependent insulin release.

Fig. 3 Scan rate effects on the layer edge current.

Fig. 2 Stratigraphic profile of the Area 15 excavation block showing the diagnostic cultural materials and components alongside the stratigraphic sequence.

Fig. 3 Rotation experiment, setup.

Fig. 1 Product lifetime distributions for the eight industrial use sectors plotted as log-normal probability distribution functions (PDF). Product lifetime.

Fig. 5 Panel appearance computation.

Fig. 1 Reference-fixing experiment, setup.

Fig. 5 Structural photocycle for DmCry.

Fig. 1 Bioinspired design of AAD for promoting wound contraction.

Fig. 3 Affective responses by exchange condition (PR and RE), level of redistribution (0 = random, one-card, and two-card exchange), and outcome as winner.

Fig. 1 Proportions of normative beliefs by exchange condition, level of redistribution (0 = random, one-card, and two-card exchange), and outcome as winner.

Fig. 1 Distribution of total and fake news shares.

Fig. 3 1D NMR. 1D NMR. Time-domain (left) and frequency-domain (right) NV NMR signals for (A) water, (B) trimethyl phosphate (TMP), and (C) 1,4-difluorobenzene.

Fig. 2 2D QWs of different propagation lengths.

Fig. 4 EUV TG signal from Si.

Fig. 2 Dissolution mechanism of nylons in the TFA:acetone mixture.

Fig. 1 Histograms of the number of first messages received by men and women in each of our four cities. Histograms of the number of first messages received.

Fig. 5 Schematic phase diagrams of Ising spin systems and Mott transition systems. Schematic phase diagrams of Ising spin systems and Mott transition systems.

Fig. 1 Cross-sectional images of He-implanted V/Cu/V samples.

Fig. 2 Magnetic properties of FGT/Pt bilayer.

Fig. 3 Characterization of the current-induced effective fields.

Fig. 2 Results of the learning and testing phases.

Fig. 3 Production of protein and Fe(II) at the end of growth correlated with increasing concentrations of ferrihydrite in the media that contained 0.2.

Fig. 2 Schematic drawings of Göbekli Tepe skulls.

Fig. 2 NH3, NOx, SO2, and NMVOC emission changes triggered by the JJJ clean air policy. NH3, NOx, SO2, and NMVOC emission changes triggered by the JJJ.

THz pulse-pump optical reflectivity probe spectroscopy on Nd2CuO4

Fig. 4 Relationships between light and economic parameters.

Fig. 5 Comparison of the liquid products generated from photocatalytic CO2 reduction reactions (CO2RR) and CO reduction reactions (CORR) on two catalysts.

Schematic of the proposed brain-controlled assistive hearing device

Fig. 1 Location of the Jirzankal Cemetery.

Fig. 4 CO2 emission changes triggered by the JJJ clean air policy.

Fig. 5 Potential-energy energy profiles of 1-HAQ.

Fig. 1 Structural and electrical properties of Bi2Se3/BaFe12O19.

Fig. 3 Maximal energy intake.

Fig. 2 Comparison of the observed DRs and the estimates by the VR model and FL. Comparison of the observed DRs and the estimates by the VR model and FL.

Fig. 3 Characterization of translational and rotational diffusion of platelets. Characterization of translational and rotational diffusion of platelets.

Fig. 3 Electronic conductivity studies.

Fig. 1 Schematic depiction of a paradigm for rapid and guided discovery of materials through iterative combination of ML with HiTp experimentation. Schematic.

Fig. 2 Large-scale μXRF and EDS characterization of the text-containing side of the TS. Large-scale μXRF and EDS characterization of the text-containing.

Fig. 4 Spatial mapping of the distribution and intensity of industrial fishing catch. Spatial mapping of the distribution and intensity of industrial fishing.

Fig. 4 Single-particle contact angle measurements.

Fig. 5 Density plots showing the relationship between growth responses to extreme events and site-level mean precipitation from all sites (N = 1314). Density.

Fig. 3 Performance of the generative model G, with and without stack-augmented memory. Performance of the generative model G, with and without stack-augmented.

Fig. 4 Behavior of resistance peak near density nm = 5.

Fig. 2 Comparison between the different reflective metasurface proposals when θi = 0° and θr = 70°. Comparison between the different reflective metasurface.

The combined signal spectra of PSD for protons and helium nuclei

Fig. 4 Scaling laws distinguish biochemical networks from random networks across levels of organization. Scaling laws distinguish biochemical networks.

Fig. 4 Analysis of charge storage mechanism in ZnxCo1−xO NRs.

Fig. 3 Calculated electronic structure of ZrCoBi.

Fig. 5 Schematics illustrating enhancement in April tornado activity due to SST. Schematics illustrating enhancement in April tornado activity due to SST.

Fig. 3 Temperature-dependent heat capacity of YbTM2Zn20.

Presentation transcript:

Fig. 1 Reaction investigation using single-molecule charge transport measurement and simultaneous NMR characterization. Reaction investigation using single-molecule charge transport measurement and simultaneous NMR characterization. (A) Schematic of the MCBJ technique for in situ single-molecule conductance measurement. The Diels-Alder reaction axis (blue arrow) is orthogonal to the direction of electric field Fz (red arrow) and parallel to the y axis, while the reaction axis of the subsequent aromatization is proposed to be nonorthogonal to the electric field. (B) The left column shows the Diels-Alder reaction between 3,6-di(4-pyridyl)-1,2,4,5-tetrazine (a) and 2,3-dihydrofuran to form compound b, which goes through an aromatization process to form compound c. The single-molecule conductance of each compound was characterized in the right column through conductance histograms: a at 10−4.45G0, b at 10−3.91G0, and c at 10−4.72G0 (purple for a, green for b, and blue for c). Each histogram was constructed from 3000 individual conductance-distance traces, with typical traces shown in the inset of each panel. Monitoring the complete transformation from a to c through 1H NMR (C) for 26 hours and conductance (D) for 4.7 hours. Each conductance histogram was constructed from approximately 300 conductance-distance traces that were collected in 5-min intervals, and the histograms were analyzed by Gaussian fitting to determine the area ratio between different components. The dashed lines represent the conductance value of each compound. Xiaoyan Huang et al. Sci Adv 2019;5:eaaw3072 Copyright © 2019 The Authors, some rights reserved; exclusive licensee American Association for the Advancement of Science. No claim to original U.S. Government Works. Distributed under a Creative Commons Attribution NonCommercial License 4.0 (CC BY-NC).