Robert J. Holiday, Chan Ho Kwon, Christopher J. Annesley and F

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Presentation transcript:

Vibrational Energy Disposal and the Spectator Model for the Reaction of CH3D with Cl Robert J. Holiday, Chan Ho Kwon, Christopher J. Annesley and F. Fleming Crim University of Wisconsin-Madison

How do vibrations affect reactions?

Local vs Normal modes

Spectator Model

Product Distributions

Product Distributions

Product Distributions

Conclusions Vibrational excitation of C-H overtone stretches enhance the H abstraction rate The |110>|0> mode reacts to produce C-H stretch excited CH2D products, while |200>|0> yields ground state products This provides support for the spectator model

Thanks F. Fleming Crim Funding: NSF

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