Wen-Jun Yue, Cheng-Yuan Zhang, Liang Yin

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Presentation transcript:

Wen-Jun Yue, Cheng-Yuan Zhang, Liang Yin Asymmetric Vinylogous Aldol-type Reactions of Aldehydes with Allyl Phosphonate and Sulfone Wen-Jun Yue, Cheng-Yuan Zhang, Liang Yin iScience Volume 14, Pages 88-99 (April 2019) DOI: 10.1016/j.isci.2019.03.010 Copyright © 2019 The Author(s) Terms and Conditions

iScience 2019 14, 88-99DOI: (10.1016/j.isci.2019.03.010) Copyright © 2019 The Author(s) Terms and Conditions

Scheme 1 Aldol-type Reactions of Aldehydes with Allyl Phosphonate and Sulfone and Selected Natural Products Synthesized with Horner-Wadsworth-Emmons and Julia Olefinations iScience 2019 14, 88-99DOI: (10.1016/j.isci.2019.03.010) Copyright © 2019 The Author(s) Terms and Conditions

Scheme 2 Trials for retro-Aldol Reactions of α-Adducts and γ-Adducts iScience 2019 14, 88-99DOI: (10.1016/j.isci.2019.03.010) Copyright © 2019 The Author(s) Terms and Conditions

Scheme 3 Transformations of the Vinylogous Products iScience 2019 14, 88-99DOI: (10.1016/j.isci.2019.03.010) Copyright © 2019 The Author(s) Terms and Conditions

iScience 2019 14, 88-99DOI: (10.1016/j.isci.2019.03.010) Copyright © 2019 The Author(s) Terms and Conditions