Fig. 5 CLSM of samples with a 2.5-μm mesoporous Al2O3 layer.

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Fig. 5 CLSM of samples with a 2.5-μm mesoporous Al2O3 layer. CLSM of samples with a 2.5-μm mesoporous Al2O3 layer. Emission between 500 and 550 nm attributed to PbI2 was assigned green, and emission between 700 and 800 nm attributed to perovskite was assigned red. The color saturation scales with the emission intensity. (A) Schematic showing planes parallel to the sample surface and the cross section, showing the different parts of the sample being imaged. (B) Composite pseudocolor image of the surface of a sample of intermediate conversion dipped for 60 s. Scale bar, 5 μm. (C) Composite pseudocolor cross-sectional image of the same sample showing the perovskite capping layer over the unconverted PbI2 in the mesoporous layer. Scale bar, 1 μm. (D) Normalized emission intensity showing horizontally averaged values of PbI2 emission and perovskite emission across the depth of the sample in (C). (E) Composite pseudocolor cross-sectional image of a sample of nearly complete conversion showing trapped, unconverted PbI2 in the mesoporous layer. Scale bar, 2 μm. Amita Ummadisingu, and Michael Grätzel Sci Adv 2018;4:e1701402 Copyright © 2018 The Authors, some rights reserved; exclusive licensee American Association for the Advancement of Science. No claim to original U.S. Government Works. Distributed under a Creative Commons Attribution NonCommercial License 4.0 (CC BY-NC).