Does the sulfur content of calcite microfossils reflect seawater [CO3=]?

Slides:



Advertisements
Similar presentations
Formation of Calcium Carbonate
Advertisements

Unit 5: Minerals.
Phase Diagram for Water
Dissociation and pH Dissociation of weak acids/bases controlled by pH Knowing the total amount of S and pH, we can calculate activities of all species.
Deptt. Of Applied Sciences Govt. Polytechnic College For Girls Patiala Presented By- Dr. Raman Rani Mittal M.Sc., M.Phil, Ph.D. (Chemistry) 1.
GEOCHEMICAL AND STABLE ISOTOPE CHARACTERIZATION OF DRIP WATER FROM POSTOJNA CAVE, SLOVENIA Magda Mandić 1 Andrej Mihevc 2, Albrecht.
OVERVIEW OF SEDIMENTARY AQUIFERS Small pores CAPABLE OF FILTERING WATER Complex flow paths through small pores yields LOW FLOW VELOCITIES What does this.
Carbon Cycle. Carbon Carbon exists in the nonliving environment as: Carbon dioxide (CO2) Carbonic acid ( HCO 3 − ) Carbonate rocks (limestone and coral.
Lecture 2 - Major Ions in Sea Water Why do we care about the major ions? What is the composition of seawater? What defines Major Ions? What are their concentrations?
Limiting Reagent and Percent Yield
Bound and Dissolved Oxygen in the Blood of Most Animals.
Lesson: Mixtures & Compounds. Science Differentiation in action A mixture is made of two or more substances mingled together but not chemically combined.
The Carbon Cycle The carbon cycle describes the exchange of carbon atoms between various reservoirs within the earth system. The carbon cycle is a geochemical.
Carbon Dioxide and Carbonate system Carbon cycle - Why is it important? 1. Regulates temperature of the planet 2. Important for life in the ocean 3. Regulates.
Lecture 2 - Major Ions in Sea Water What is the composition of seawater? What defines Major Ions? What are their concentrations? What are their properties?
THE RELATIONSHIP BETWEEN H2CO3* AND HCO3-
Lecture 24 10/31/05. Finding endpoint with pH electrode.
PH and Salts Colligative Properties of Seawater vs. Freshwater Determining Salinity, Temperature, and Depth.
HOW INCREASING CARBON DIOXIDE DUE TO CLIMATE CHANGE WILL AFFECT SOYBEAN Kaitlin Togliatti.
Effects of global warming on the world’s oceans Ashley A. Emerson.
Productivity and the Coral Symbiosis II. Polyp can survive extended periods with no external food source Tight internal N-cycling and algal PS.
Parasitism and Symbiosis: isotope effects in mistletoe and foraminifera 1998)
10.2 Oxygen Dissociation Curves
Strong and Weak Acids and Bases
IB Group Internal Assessment NIS: Rik Aikman, Wonwoo Choi FIS: Ji-Eun Park, Yumi Nishikawa.
Learning Targets “I Can..” Describe the contents of smog and how smog contributes to the formation of acid rain. Study the effect of dissolved CO 2 on.
Class The Oceans More on the chemistry of the Oceans... DISSOLVED GASES IN SEA WATER Solubility of atmospheric gases Solubility of atmospheric gases.
Chapter 2: Chemical Basis of Life Part II: Chemical Reactions Acids and Bases Inorganic Substances.
Chapter 6: Neutralizing the Threat of Acid Rain Is normal rain acidic? Is acid rain worse in some parts of the country? Is there a way to “neutralize”
Physical Properties of Seawater Thermal Properties of Water.
CHEMICAL OCEANOGRAPHY
The Carbon Cycle. Carbon Dioxide and Carbonate system Why is it important? 1. CO 2 regulates temperature of the planet 2. Important for life in the ocean.
General Chemistry Element –composed of atoms Nucleus –protons (+) and neutrons (0) Electrons (-)
Saturated solution – no more solute will dissolve solubility product constant – equilibrium constant for ionic compounds that are only slightly soluble.
Does Carbonate Ion Influence Foraminiferal Mg/Ca? Ed Boyle Department of Earth, Atm., and Planetary Sciences Massachusetts Institute of Technology Cambridge.
Karst Chemistry II. Conductivity – Specific Conductance Conductance – the electrical conductivity of aqueous solution, and is directly related to the.
The Carbon Cycle. Carbon Dioxide and Carbonate system Why is it important? 1. CO 2 regulates temperature of the planet 2. Important for life in the ocean.
Caroline De Bodt, Quentin d’Hoop, Jérôme Harlay and Lei Chou
The Carbon Cycle. Carbon Dioxide and Carbonate system Why is it important? 1. Regulates temperature of the planet 2. Important for life in the ocean 3.
Soils are formed as a result of
PH and Chemical Equilibrium. Acid-base balance Water can separate to form ions H + and OH - In fresh water, these ions are equally balanced An imbalance.
VARIATIONS IN SALINITY OF SEAWATER
1 Basic Ocean Chemistry AOSC 620 Why do we care? Source of much food. Sink for much CO 2 and acids. Biodiversity. Great store and transport of heat. Source.
Fig. 7-CO, p Fig. 7-1, p. 186 Condensation Precipitation 111,000 Precipitation 385,000 Transpiration and Glaciers Evaporation 425,000 Groundwater.
Ocean Properties and Chemistry
Productivity and the Coral Symbiosis III. Overall productivity of the reef: gC/m 2 /d this is organic carbon production must also consider.
© 2016 Cengage Learning. All Rights Reserved. 7 Oceanography, An Invitation to Marine Science | 9e Tom Garrison Ocean Chemistry.
Carbon and Nitrogen Cycles in the Ocean MP 2.2. The Carbon Cycle All animals and most cells release CO 2. Plants use it to make food. CO 2 is highly soluble.
Marine Biology What it takes to be alive. © 2002 Brooks/Cole, a division of Thomson Learning, Inc. Being Alive What are characteristics of all living.
Buffering Capacity: Seawater CO 2 Chemistry Scripps Classroom Connectionhttp://earthref/SCC.
Compounds T. M. Yeung 2000 Sugar Brown sugar Main component: Sucrose, C 12 H 22 O 11 Carbohydrate: Carbon, Hydrogen & Oxygen.
Working Group: Seawater Carbonate Chemistry Common themes, considerations and issues: existing established best practices for methods (Dickson et al.,
The Carbon Cycle. Carbon Dioxide and Carbonate system Why is it important? 1. Regulates temperature of the planet 2. Important for life in the ocean 3.
Acid Rain and the Greenhouse Effect Section 25.4.
Analysis Questions: 1.What does pH measure? the concentration (not “amount”) of hydrogen (H+) ions in a solution. 2.Which pH has the highest concentration.
Chemical & Physical Properties of SeaWater
Acidification of the Ocean. Deep sea sequestering Storing CO2 in the sea Less CO2 in the atmosphere Acidifies the Ocean Dangerous for marine life.
ΜΕΤΑΣΥΛΛΕΚΤΙΚΗ ΦΥΣΙΟΛΟΓΙΑ ΕΡΓΑΣΤΗΡΙΟ 3. Μετασυλλεκτική Εργ3-Λιοσάτου Γ.2 ΒΙΟΛΟΓΙΚΟΙ ΠΑΡΑΓΟΝΤΕΣ ΠΟΥ ΕΠΗΡΕΑΖΟΥΝ ΤΗ ΦΘΟΡΑ ΤΩΝ ΟΠΩΡΟΚΗΠΕΥΤΙΚΩΝ Αναπνοή Η λειτουργία.
Soil Chemistry.
Warm-up: Pick up a square of paper and answer the following.
15.2 NOTES Acid Rain and Concentration
CC9 - Calculating Involving Masses (p26-30)
Water Chemistry: Hardness
Earth History Limestone
OVERVIEW OF SEDIMENTARY AQUIFERS
اثرات گرمايش جهاني تغييرات آب و هوا، تأثيرات عميق و شديدي بر بسياري از عوامل اساسي موثر بر سلامت از جمله : آب، غذا، هوا و محيط زيست دارد كه اين مورد خود.
How many moles of water are made by
Chemistry of seawater Salt pH Gases Nutrients.
Organic Compounds Notes
Composition of Seawater
Presentation transcript:

Does the sulfur content of calcite microfossils reflect seawater [CO3=]? The [SO4=] concentration of seawater is constant The [CO3=] concentration of seawater varies with pH and total dissolved inorganic carbon dioxide. Hence the [SO4=]/ [CO3=] ratio of seawater is variable. When calcite microfossils are formed (incorporating ~0.1% of SO4= into CaCO3), do they reflect the [SO4=]/ [CO3=] of the seawater the organisms grow in?

Little Bahama Bank Field Calibration

The normalized SO42- values to a constant Mg content yield SO42- profile, which is negatively correlated with CO32- as expected.