Theory Reveals Novel Chemistry of Photonic Molecules

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Presentation transcript:

Theory Reveals Novel Chemistry of Photonic Molecules Matthew Du Chem Volume 5, Issue 5, Pages 1009-1011 (May 2019) DOI: 10.1016/j.chempr.2019.04.012 Copyright © 2019 Terms and Conditions

Figure 1 Remote Control of Chemistry with Optical Cavities (A) Simplified visualization. Top: a “pump” pulse excites a polariton whose character is predominantly remote catalyst (RC) and its cavity. Bottom: as a result, a subsequent “probe” pulse efficiently excites a polariton whose character is predominantly reactant and its cavity, and the product is formed. (B) Energetic representation. Left: after pump excitation, the highest polariton relaxes to RC dark states. Right: as a result of the excited RC population just formed, the lowest polariton becomes resonant with the probe pulse and gains reactant character; efficient transfer into the product-yielding state occurs. Adapted from Du et al.2 Chem 2019 5, 1009-1011DOI: (10.1016/j.chempr.2019.04.012) Copyright © 2019 Terms and Conditions

Chem 2019 5, 1009-1011DOI: (10.1016/j.chempr.2019.04.012) Copyright © 2019 Terms and Conditions