Matt Turnbull Host-guest materials Alex Kersting Mixed metal amides James Prendergast Magnesium based systems 4 th UK / Japan Workshop on Solid State Hydrogen.

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Presentation transcript:

Matt Turnbull Host-guest materials Alex Kersting Mixed metal amides James Prendergast Magnesium based systems 4 th UK / Japan Workshop on Solid State Hydrogen Storage, Sendai Hydrogen Storage Chemistry Group Paul Anderson Phil Chater Amide-borohydrides Ian Evans Metallated ammonia borane Chao Zhao Framework materials David Hewett New systems with enhanced reversibility the discovery, synthesis and primary characterization of new materials with potential for hydrogen storage/delivery chemical modification of new and existing materials to improve their performance

Chemically activated magnesium hydride

Li 4 BH 4 (NH 2 ) 3 Li 2 BH 4 NH 2 Na 2 BH 4 NH 2 Compounds containing both protic and hydridic hydrogens 4 th UK / Japan Workshop on Solid State Hydrogen Storage, Sendai Hδ+Hδ+δ-Hδ-H H2H2

TPD 2LiNH 2 + LiBH 4 → Li 3 BN 2 + 4H 2 ( 4 / 3 H 2 per Li) MRS Fall Meeting, Boston, 30 November–4 December 2009 LiNH 2 + LiBH 4 → 2LiH + BN + 2H 2 (1H 2 per Li)

Current projects EPSRC SUPERGEN UK Sustainable Hydrogen Energy Consortium with 12 UK partners IPHE approved project Combination of Amine Boranes with MgH 2 & LiNH 2 for High Capacity Reversible Hydrogen Storage with 8 international partners AWM Science City Hydrogen Energy Project Collaborators (Met & Mat) Allan Walton, Dan Reed, David Book (Met & Mat) Bill David (ISIS) John Hanna, Mark Smith (Warwick) Sustainable Power Generation and Supply Consortium UK Sustainable Hydrogen Energy Consortium Hydrogen Energy Project Advanced Materials 1 International Partnership for the Hydrogen Economy