REESS SCOPE as a first step 1 RESS-6-13.  This sub-group has addressed to develop the new REESS safety requirements for higher BEV/PHEV/HEV production.

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Presentation transcript:

REESS SCOPE as a first step 1 RESS-6-13

 This sub-group has addressed to develop the new REESS safety requirements for higher BEV/PHEV/HEV production volumes in the near future  Several types of REESS exist.  Non-water based electrolyte (e.g. Li-ion)  Water based electrolyte (e.g. NiMH, Lead-acid)  Molten salt, Molten metal (e.g. ZEBRA, NaS)  Capacitors, etc.  At present and foreseeable future, the most of REESS for BEV/PHEV/HEV will use electro-chemical battery with Non-water based electrolyte or Water based electrolyte REESS SCOPE to be addressed as a first step 2

 The major risks considered by the group is Fire/Explosion, while other safety aspect has been covered by existing regulations (ref. RESS-1-4)  Flammability of the electrolyte is the key element to assess the potential risks of Fire/Explosion  The potential risks are significantly different between  Flammable, non-water based electrolyte (Li-ion ) and  Non-flammable, water based electrolyte (NiMH, Lead-acid) REESS SCOPE to be addressed as a first step 3

Li-ionNiMHLead-acid Reaction mechanism carrier Lituim-ionHydroxide-ionProton cathode Lithium metal oxideNickel oxyhydroxideLead dioxide anode CarbonHydrogen storage alloyLead Flash point charger separator charge discharge Lithium ion ( Li + ) +- electrolyte separator Hydroxide ( OH - ) +- charger charge discharge separator +- charger charge discharge electrolyte Proton ( H + ) electrolyte Organic electrolyte (Flammable) Aqueous alkaline (non-Flammable) ℃ None No ignition point Non-Flammable Dilute sulfuric acid (non-Flammable) Non-Flammable About 450 ℃ (High volatile) vol% Auto-flammable limit Electrolyte Auto-ignition point None Difference between Flammable and non-Flammable 4

Organic electrolyte for Lithium ion cell Aqueous alkaline electrolyte for Nickel Metal Hydride cell Flammability Test of electrolyte Difference between Flammable and non-Flammable 5

6  The R100/02 draft has been discussed focusing on the Li-ion which uses flammable electrolyte.  It is inappropriate to simply apply to the other batteries without assessing the degree of the potential risks and the expected effect of the regulatory requirements. *The potential risk of non-flammable electrolytes are far below than that of flammable electrolyte, as those has no flash point nor auto-ignition point. Conclusion The appropriate requirements for non-flammable should be developed for REESS as a next step after through examination of the potential risks and the effectiveness.

End