Name: Chloe Yau Class: F.3B Class no: 36

 Formula : PBr 3  Physical properties: Melting point : °C (231.7 K) Boiling point: °C (446.4 K) Physical state at room temperature: liquid Colour: colourless Density: g/cm 3 Solubility in water: rapid hydrolysis

Laboratory Preparation: PBr 3 is prepared by treating phosphorus with bromine.  Reactivity: Phosphorus tribromide, like PCl 3 and PF 3, has both properties of a Lewis base and a Lewis acid. The most important reaction of PBr 3 is with alcohols, where it replaces an OH group with a bromine atom to produce an alkyl bromide. PBr 3 converts carboxylic acids to acyl bromides. PBr 3 is a reasonably strong reducing agent, and the oxidation of PBr 3 with oxygen gas is more vigorous than seen with PCl 3. It gives an explosive reaction that forms P 2 O 5 and Br 2. PBr 3 evolves corrosive HBr, is toxic, and reacts violently with water and alcohols.

 Potential hazards: Corrosive Toxic Irritant

 Uses: For conversion of primary or secondary alcohols to alkyl bromides As a catalyst for the α-bromination of carboxylic acids On a commercial scale, phosphorus tribromide is used in the manufacture of pharmaceuticals such as alprazolam, methohexital and fenoprofen. It is also a potent fire suppression agent marketed under the name PhostrEx. Used as an analytical reagent to test for sugar and oxygen.

 romide romide  tribromide#ixzz1JnALyT4chttp:// tribromide#ixzz1JnALyT4c