Lecture ELEVEN Metamorphism of carbonate rocks (Metcarbonates)

Slides:



Advertisements
Similar presentations
Metamorphic Phase Diagrams
Advertisements

Chapter 29: Metamorphism of Calcareous and Ultramafic Rocks
Mineral Structures Silicates are classified on the basis of Si-O polymerism the [SiO 4 ] 4- tetrahedron.
METAMORPHIC MINERALS Prepared by Dr. F. Clark,
Metamorphism – changes in mineralogy and texture brought about by perturbations in heat and pressure Compositional changes are generally restricted to.
Metamorphism Changes in Rock Composition or Texture
Lecture SEVEN Lecture SEVEN Nomenclature of Metamorphic rocks.
METAMORPHISM.
FT 2 report due Thursday, Nov. 7, by 5 PM!FT 2 report due Thursday, Nov. 7, by 5 PM!
Chapter 22: A Classification of Metamorphic Rocks A good name is a concise way of imparting information about a rock.
Mahrous M. Abu El-Enen Faculty of Science, Mansoura University Igneous and metamorphic Petrology.
Introduction to Metamorphic Petrology
Igneous Rocks. Classification of Igneous Rocks Most Abundant Elements: O, Si, Al, Fe, Ca, Mg, K, Na Calculate Elements as Oxides (Account for O) How Much.
Lecture NINE Metamorphism of pelitic rocks Lecture NINE Metamorphism of pelitic rocks (Metapelites – Part II)
Classification and Facies Wikipedia. Today Updates: Not today Lecture outline: - Rock classification - Facies.
Regional Pelitic Rocks Reading: Winter, Chapter 28.
Lecture EIGHT Metamorphism of pelitic rocks (Metapelites – Part I)
Intersecting Isograds at Whetstone Lake Dugald Carmichael (1970) Journal of Petrology, 11, l Pelitic and calcareous rocks l Wide range of chemical.
Chapter 23: Metamorphic Textures Textures are small-scale features of rocks Textures are small-scale features of rocks
GEOS 254 Lecture 2: FELDSPARS
Metamorphic Reactions Reading: Winter Chapter 26.
Measurement of Carbonate Minerals in Aerosol Samples- A Preliminary Study Johann Engelbrecht Desert Research Institute.
Phase Diagrams Best, Chapter 14.
Metamorphic Facies Best, Chapter 10.
Metamorphism and Metamorphic Rocks
Calcareous and Ultramafic Rocks Reading: Winter Chapter 29.
Lecture TEN Metamorphism of Basic Igneous Rock Lecture TEN Metamorphism of Basic Igneous Rock (Metabasites)
Descriptions of Rock Forming Minerals: All the following minerals are made of silica tetrahedrons, either alone or combined with other elements.
Metamorphism Changes in rocks due to increasing P-T conditions and/or interaction with fluids.
Metamorphic Facies and Mineral Assemblages
Chapter 16 Mineral genesis. Mineral genesis and genetic mineralogy Genesis = origin Genesis = origin –Primary crystallization –Subsequent history: transitions,
Introduction to the Metamorphism of Carbonate Rocks
EARTH MATERIALS III Rock-forming minerals: silicates Professor Peter Doyle
MOST IMPORTANT MINERAL SUITE: The Silicate Minerals
Lecture 6 變質岩分類與各論. Definition of metamorphism The mineralogical and structural adjustment of solid rocks to physical and chemical conditions that have.
Metamorphism Changes in Rock Composition or Texture Due to Heat, Pressure and Action of Fluids.
Geology 1303-Block 2 Minerals Rock Cycle Igneous Rocks-(including volcanoes&plutons) Sedimentary Rocks Metamorphic rocks Exam 2 :Oct 18 th WED -To be Confirmed.
Reading: Winter, Chapter 30
Origin Metamorphic rocks arise from the transformation of existing rock types Process called metamorphism, which means "change in form". The original rock.
Concept of Index Minerals
Metamorphic Rocks. What causes metamorphism? Heat Pressure Reaction with fluids.
Chapter 10 - B Identification of minerals with the petrographic microscope.
Metamorphic Rocks Francis, paragoniteNaAl 2 (AlSi 3 O 10 (OH) 2 muscoviteKAl 2 (AlSi 3 O 10 (OH) 2 pyrophylliteAl 2 Si 4 O 10 (OH) 2 andalusiteAl.
The Minerals of Metamorphosed Mafic Rocks Mafic rocks generally have igneous protoliths: basalt and its coarse- grained equivalent, gabbro.
UNIT - 6.  Metamorphism (from the Greek words for “changing form”) is the process by which rising temperature and changes in other environmental conditions.
THE LANGUAGE OF THE EARTH – PART III
Chapter 24. Stable Mineral Assemblages in Metamorphic Rocks
Metamorphism of Calcareous/Ultramafic Rocks
IV- Sillimanite zone zone Sillimanite in this zone can occur due to the occurrence of the polymorphic solid-solid reaction: andalusite  sillimanite but.
Lecture FOUR Metamorphic Reactions and Protoliths of Metamorphic Rocks
Metamorphic Rocks, Part 4 CONTACT AND DYNAMIC METAMORPHIC ROCKS
Hornblende Plag Metabasites Francis, 2014 garnet.
Lecture TWELVE Metamorphism of Ultramafic rocks Lecture TWELVE Metamorphism of Ultramafic rocks (Metaultramafics)
AFM Diagram Due to extensive Mg-Fe solid solution in biotite and garnet, much of the area is dominated by 2-phase fields with tie- lines (really 4-phase.
Metamorphism and Metamorphic Rocks Physical Geology.
G EOL 2312 I GNEOUS AND M ETAMORPHIC P ETROLOGY Lecture 22 Metamorphism of Calcareous and Ultramafic Rocks April 13, 2016.
8. METAMORPHIC ROCKS.
Geol 2312 Igneous and Metamorphic Petrology
Metamorphic Rocks Lecture
Geol 2312 Igneous and Metamorphic Petrology
Metamorphism Changes in Rock Composition or Texture
Metabasites / Metacarbonates
Metamorphism Changes in Rock Composition or Texture
Metamorphic Petrology Francis, 2014
Metamorphic Petrology
Metamorphic rocks.
Triangular compatibility diagrams 2
Chapter 29: Metamorphism of Calcareous and Ultramafic Rocks
Metamorphic fluids Lecture 9.
Metabasites / Metacarbonates
Presentation transcript:

Lecture ELEVEN Metamorphism of carbonate rocks (Metcarbonates)

What is the Metacarbonates? Metacarbonates, are metamorphosed calcareous (limestone and dolomite) rocks in which the carbonate component is predominant, with granoblastic polygonal texture Metacarbonates include: i) Marbles are nearly pure carbonate (carbonate >50%) ii) Calc-silicate rocks: carbonate is subordinate (carbonate <50%) and may be composed of Ca-Mg-Fe-Al silicate minerals, such as diopside, grossular, Ca-amphiboles, vesuvianite, epidote, wollastonite, plagioclase, talc, anthophyllite, etc. iii) Skarn: calc-silicate rock formed by metasomatism between carbonates and silicate-rich rocks or fluids Carbonate rocks are predominantly carbonate minerals, usually limestone or dolostone. They may be pure carbonate, or they may contain variable amounts of other precipitates (such as chert or hematite) or detrital material (sand, clays, etc.) Chemically, the carbonate rocks are rich in CaO, CO2, MgO, and mad may SiO2, Al2O3, FeO, and other subordinate oxides if the carbonate are impure.

Mineralogy of Metacarbonates Metacarbonate contain the following mineral assemblage: Carbonate minerals (Calcite and dolomite), Amphibole (anthophyllite Enstatite, Tremolite) Pyroxene (Diopside) Olivine talc, wollastonite quartz

Pure limestone and dolomite Impure limestone and dolomite The metacrbonates will discussed for metamorphism in the following conditions: Pure limestone and dolomite Impure limestone and dolomite

-1- Pure Metacarbonates Calcite and dolomite marbles

1- Pure Carbonates (Limestone and dolomite) Metamorphism of pure carbonate rocks yielded calcite and/or dolomite marbles. Many marbles are composed only of calcite and/or dolomite with minor quartz and phyllosilicates, originally of detrital origin. A- Calcite marble The grade of metamorphism is function in grain size, where grain size increases with grade increase. At very HP, the polymorph aragonite becomes stable and aragonite marble is known from high pressure terrains. At HT/LP (>600°C) calcite and quartz react to produce wollasonite and CO2. The reaction occurs only at high temperature thermal aureole, and is inhibited by high fluid pressures of CO2. CaCO3 +SiO2  CaSiO3 + CO2

1- Pure Carbonates (Limestone and dolomite) A- Dolomite marble At HT/LP, dolomite marble loses CO2 to form periclase (MgO) in condition <900 °C, and consequently reacts with water to form brucite (MgO(OH)2). Therefore, the common result of decarbonation of dolomite or dolomitic marble is a mixture of brucite and calcite. Quartz bearing dolomitic marbles (calcite + dolomite + quartz) develop a characteristic sequence of Ca- and/or Mg-silicate as follows: (i) talc dolomite + qurtz + H2O = talc + calcite + CO2 (ii) tremolite in the greenschist facies, talc + calcite + quartz = tremolite + H2O + CO2 (quartz rich) talc+calcite = tremolite + dolomite + CO2 + H2O (quartz poor)

1- Pure Carbonates (Limestone and dolomite) A- Dolomite marble, cont. (iii) diopside and/or forsterite in the amphibolite facies tremolite+calcite+quartz = diopside+H2O +CO2 tremolite + dolomite = forsterite + calcite + H2O + CO2 And, (iv) diopside + forsterite at higher grade. tremolite + calcite = diopside + forsterite + H2O+CO2 Sheet-silicate impurity in calcite and dolomite marble adds variety by the following Al-bearing minerals to feature in the assemblage: typically they include zoisite, epidote and Ca-rich garnet in the greenschist facies and anorthite in the amphibolite facies.

Metamorphic zones developed in regionally metamorphosed dolomitic rocks of the Lepontine Alps

-2- Metamorphism of impure carbonates and marls (Calc-silicates)

2- Calc-silicates Calc-silicates are rocks rich in Ca-Mg-silicate minerals but poor in carbonate, They form via the metamorphism of very impure calcite or dolomite limestones, or from limy mudstones (marls). Since calc–silicates contain significant amounts of other chemical components, such as Al, K and Fe, minerals such as zoisite (epidote group), garnet, Ca-plagioclase, K-feldspar, hornblende and diopside could formed. A generalized zonal sequence can be summarized as follows:

I- Ankerite zone II- Biotite zone The lowest grade rocks It characterized by the assemblage ankerite Ca(Mg,Fe)(CO3)2) + quartz + albite + muscovite ± chlorite II- Biotite zone This zone is characterized by the coexistence of biotite and chlorite without amphibole, via a reaction such as: Ms +Qtz + ankerite + H2O  Cal + Chl + Bt + CO2 The upper part of this zone also characterize by the replacement of albite by a more Ca-rich plagioclase and a reduction in the amount of muscovite present: Chl + Cal + Ms + Qtz + Ab  Bt + Pl + H2O + CO2

III- Amphibole zone IV- Zoisite zone V- Diopside zone The appearance of Ca-amphibole is accompanied by a further increase in the Ca content of the plagioclase: Chl + Cal + Qtz + Pl  Ca-amph + Ca-Pl + H2O + CO2 IV- Zoisite zone Zoisite (Ca2(Al,Fe)3[SiO4](OH)) often first appears rimming plagioclase at contacts with calcite grains, suggesting growth is due to the reaction: Ca-plagioclase + calcite + H2O  zoisite + CO2 V- Diopside zone At the highest grades diopside appears due to the breakdown of amphibole: Ca-amphibole + calcite + quartz  diopside + H2O + CO2