1. Introduction Study Area Objectives Literature review Methodology Results Conclusions 2.

Slides:



Advertisements
Similar presentations
The Properties of Gases
Advertisements

Lecture 20. Adsorption Phenomena
The influence of wettability and carbon dioxide injection on hydrocarbon recovery Saif Al Sayari Martin J. Blunt.
GASES. General Properties of Gases There is a lot of “free” space in a gas. Gases can be expanded infinitely. Gases fill containers uniformly and completely.
99 學年度第一學期專題討論 99 學年度第一學期專題討論 Sorption of methane and CO 2 for enhanced coalbed methane recovery and carbon dioxide sequestration Prusty, B. K., 2008.
Unit 1: Gases and Stoichiometry Geoff Hackett and Adam Serck.
Jan – Dec, 2006 University of Alaska – Fairbanks Pacific Northwest National Laboratory British Petroleum Exploration Alaska Injection of CO 2 for Recovery.
Advanced Thermodynamics Note 6 Applications of Thermodynamics to Flow Processes Lecturer: 郭修伯.
Flow scheme of gas extraction from solids Chapter 3 Supercritical Fluid Extraction from Solids.
Gas Laws Chapter 14. Properties of Gases  Gases are easily compressed because of the space between the particles in the gas.
Overburden Pressure Affects Fracture Aperture and Permeability in a Stress- Sensitive Reservoir Vivek Muralidharan.
1 The Combustion of Hydrocarbon Fuels 朱 信 Hsin Chu Professor Dept. of Environmental Engineering National Cheng Kung University.
Joshua Condon, Richard Graver, Joseph Saah, Shekhar Shah
Chapter 10 Gases No…not that kind of gas. Kinetic Molecular Theory of Gases Kinetic Molecular Theory of Gases – Based on the assumption that gas molecules.
Unconventional Petrophysical Analysis in Unconventional Reservoirs
Unit 9: Gases Ideal Gas Law. After today you will be able to… Explain what an ideal gas is Calculate an unknown pressure, temperature, volume, or amount.
 Slides 3-8 Slides 3-8 ◦ Part One: Kinetic Molecular Theory and Introduction to Gas Laws  Slides Slides ◦ Part Two: Boyle’s Law, Charles’
Measuring Gases Objectives: 1. Explain what gas pressure means and describe how it is measured. Key Terms: atmospheric pressure, barometer, manometer,
Ch. 5 Gases. Ch. 5 Topics Kinetic Molecular Theory and Gases Ideal vs. Real Gases What conditions are ideal for gases? PV=nRT PV=(m/MM)RT Know how to.
1 Thermal Physics 13 - Temperature & Kinetic Energy 15 - Laws of Thermodynamics.
Particles have LOTS of energy; moving all around Gases take on the shape and volume of their container. Gases will spread out evenly = diffusion Ruled.
Lost Ridge Klappan area Coalbed Methane potential of the anthracite Groundhog/Klappan Coalfield Northern Bowser Basin Barry Ryan New Ventures Branch Ministry.
 The average kinetic energy (energy of motion ) is directly proportional to absolute temperature (Kelvin temperature) of a gas  Example  Average energy.
General Properties of Gases There is a lot of “free” space in a gas. Gases can be expanded infinitely. Gases fill containers uniformly and completely.
Gases Kinetic Molecular Theory of Gases. A gas consists of small particles (atoms/molecules) that move randomly with rapid velocities Further Information.
CHEMISTRY April 17 th, Brainteaser FRIDAY 4/20/12 Tell me how your are going to explain what happened in your experiment and WHY it happened to.
Unit 14 Gas Laws. Properties of Gases Gas properties can be modeled using math. Model depends on— 1.V = volume of the gas (L) 2.T = temperature (Kelvin,
Gases Chapter 13 Some basics Gases have properties that are very different from solids and liquids. Gases have properties that are very different from.
Chemistry II Unit 1 Gases.
Chapter 9: Gases: Their Properties and Behavior
Analysis of the Devonian Shale in Kentucky for Potential CO 2 Sequestration and Enhanced Natural Gas Production Brandon C. Nuttall, James A. Drahovzal,
1 Gases: Ch Pressure Basic properties of gases –Expand to completely fill their container –Take the shape of their container –Have low density (compared.
Energy Analysis of Underground Coal Gasification with Simultaneous Storage of Carbon Dioxide Ali Akbar Eftekhari Hans Bruining x.
Carbon Dioxide Dr. Reid B. Grigg New Mexico Petroleum Recovery Research Center New Mexico Institute of Mining and Technology Socorro, New Mexico.
Starter S-146 List five properties of gases.. The Behavior of Gases Chapter 14.
CO 2 Sequestration in Coal Seams B. K. Prusty Ph. D. (USA) Scientist Central Institute of Mining and Fuel Research.
Improved Application of Gas Reservoir Parameters ACARP Project C10008 May 10 th 2002 Mackay Technology Transfer Update.
Chapter 5 Gases.
Chapter 13: Thermodynamics
Coal Bed Methane by Widodo W. Purwanto a Departemen Teknik Kimia b Pengkajian Energi Fakultas Teknik Universitas Indonesia.
Alternative equation for sorption data interpretation Patrick van Hemert & K-H.A.A. Wolf May 25, 2006 International Symposium CBM, Tuscaloosa.
99 學年度第二學期專題討論 99 學年度第二學期專題討論 Influence of carbon dioxide on coal permeability determined by pressure transient methods Siriwardane, H., Haljasmaa, I.,
大氣所碩一 闕珮羽. Introduction Variations in oxygen concentration in the deep ocean can strongly affect the preservation of carbon in sediment. The resulting.
Department of Chemical & Process Engineering The high pressure interactions of coal with CO 2 Implications for CO 2 disposal and CH 4 displacement from.
Unit 1 Gases. Ideal Gases Objectives 1. Compute the value of an unknown using the ideal gas law. 2. Compare and contrast real and ideal gases.
Ch. 14 The Behavior of Gases PROPERTIES OF GASES.
Gas Processes. Gas Process The thermodynamic state of a gas is defined by pressure, volume, and temperature. A “gas process” describes how gas gets from.
What volume will 1 mole of a gas occupy at STP? STP = 273K, 1.013x10 5 Pa One mole of any ideal gas occupies a volume of 22.4L at STP.
X Unit 13 – GAS LAWS. Importance of Gases  Airbags fill with N 2 gas in an accident.  Gas is generated by the decomposition of sodium azide, NaN 3 according.
M idcontinent I nteractive D igital C arbon A tlas and R elational Data B ase James A. Drahovzal, Lawrence H. Wickstrom, Timothy R.Carr, John A. Rupp,
The Impact of SCCO 2 Injection Rate on Recovery efficiency from Gas- Condensate Reservoirs: Laboratory Investigation H. Sidiq, A. Al-bari, R. Amin September.
Gases expand, diffuse, exert pressure, and can be compressed because they are in a low-density state consisting of tiny, constantly moving particles. Section.
Chapter 13 and 14. Essential Question: What are three units for pressure and how do you convert units? Warm-Up: What are the three states of matter? List.
Gases HW: read CH 13.
Chapter 5 Gases. Air Pressure & Shallow Wells Gases Are mostly empty space Occupy containers uniformly and completely The densities of gases are much.
The Properties of Gases Chapter 12. Properties of Gases (not in Notes) Gases are fluids… Fluid: (not just to describe liquids)  can describe substances.
Chemistry Chapter 5 Gases Dr. Daniel Schuerch. Gas Pressure Gas pressure is the result of simultaneous collisions of billions of rapidly moving particles.
Hemant Kumar EGEE /28/2009 DEPARTMENT OF ENERGY AND MINERAL ENGINEERING COLLEGE OF EARTH AND MINERAL SCIENCES.
Physical Science Chapter 3
Ch 12 Gases Though the chemical behavior of gases differ, all gases have very similar physical behavior Gases are distinguished from other states of matter:
X Unit 14 – GAS LAWS. Properties of Gases Gas properties are affected by certain variables. Those variables are: 1. V = volume of the gas (L) 2. T = temperature.
Ch 12 Gases Though the chemical behavior of gases differ, all gases have very similar physical behavior Basic properties of gases Expand to completely.
A New Coal-Permeability Model:
KINETIC MOLECULAR THEORY
Process simulation of switch grass gasification using Aspen Plus
The Gas Laws and Ideal Gases
Gas Laws.
How many moles of water are made by
Starter S-146 List five properties of gases..
Unit 5A Mole – Volume Relationships
Presentation transcript:

1

Introduction Study Area Objectives Literature review Methodology Results Conclusions 2

Coal bed methane production and CO 2 sequestration are the promising technology being developed as a win–win process to reduce global warming and produce a valuable energy resource. Manik (2002) used the PSU-COALCOMP reservoir simulator to understand the influence of sorption isotherms. 3

4

To study the influence of sorption isotherms. To predict the efficiency of coal seam sequestration by sweep efficiency and variable pressure distribution. 5 (

The basic well pattern is based on plans for the newest available coal seam sequestration project. (Cairns, 2003) 6 Well site AWell site B Well site C (Cairns, 2003) Fig 2. 3D well pattern in coal seam. Fig 1. Horizontal well pattern in coal seam. 915m 183m Horizontal Methane Production Wells Vertical Methane Production Well Vertical CO 2 Injection Well Horizontal CO 2 Injection Wells

Coal seam fluids generally consist of water, methane, and small amounts of other hydrocarbons, H 2 S, and carbon dioxide. These fluids can be found both in the bulk coal matrix and in the coal cleats. Fig 3. Mechanisms for flow of methane in coal seam. (Remner et al., 1984) 7 CH 4 CO 2

Simulator : PSU-COALCOMP Isotherm model : The Langmuir is a two-parameter model of the following form: c: the amount of gas that is sorbed to the solid matrix (mmol/g) λ Vλ V : the Langmuir volume constant (mmol/g) λ Pλ P : the Langmuir pressure constant (kPa) P: the pressure of the gas (kPa) 8 (Langmuir, 1918)

In an actual coal bed methane production and carbon sequestration project, kinetics can play a significant role. (Sams et al., 2003) Lumped-parameter model : 9 τ: the sorption time constant (s) D mi : the micropore diffusion coefficient(ft 2 /day) R mi : the cleat spacing(ft)

Porosity : For CBM production, the porosity is in reference to the cleat porosity and not to the matrix. cleat porosity=0.1% correction : CO 2 → mmol/g-coal CH 4 →0.0026mmol/g-coal 10 (Source :

11 (Carroll and Pashin, 2003) Fig 4. Sorption isotherms: (a)a sampling of Langmuir isotherms used in the model (b)the measured values from 26 samples within the Black Warrior Basin

12 Calculate the maximum amount of CO 2 Estimate how much would actually be sequestered Predict the changes with coal sorption properties

Production well Injection well (Cairns, 2003) Steps in the simulated production/sequestration process are as follows: Shut in the central wells for a day Inject CO2 into the coal seam stop injection CO 2 CH 4 Water Shut in 13

14 Fig 5. Thermodynamic maximum amounts of carbon dioxide that can be sequestered in coal at a gas pressure of 3500 kPa (500 psi). Langmuir Isotherm model: Table 1 Coal seam properties PropertyValue Sorption volume constant (CO 2 ) a mmol/g-coal Sorption pressure constant (CO 2 ) a kPa

Fig 6. Amount of carbon sequestered as a function of the Langmuir pressure constant and the Langmuir volume constant. Solid lines : theoretical maxima Points : simulations (psi) 15

The values from simulations < theoretical maximum, because : (1) CO 2 can not infiltrate a portion of the coal seam because of sweep inefficiency. (2) The pressure within the seam is not uniform. mole fraction of carbon 60-70% gas pressure (in psi ; 1 psi=6.89 kPa) 16

Carbon dioxide sequestered Methane produced Simulate result Theoretical maxima 50% - 70%80% - 97% Langmuir volume Direct proportionInverse proportion Langmuir pressure Inverse proportionDirect proportion 17

Langmuir volume constant (V L ) : The maximum amount of gas that can be adsorbed on a piece of coal at infinite pressure. Langmuir Pressure constant (P L ): This parameter affects the shape of the isotherm. 18 ( media/webhelp/c-te-concepts.htm)

For sequestration, the amount of CO 2 was between 50~70%. The amount of methane produced was between 80~97%. As the Langmuir volume increases and the Langmuir pressure decreases, the amount of CO 2 sequestered goes up, and the amount of methane produced decreases. 19

20