Robert J. O'Reilly1 Chapter 12 Alcohols, Phenols, Ethers, Aldehydes, and Ketones Aldehydes and Ketones

Robert J. O'Reilly2 Aldehydes and Ketones In an aldehyde, an H atom is attached to a carbonyl group Ocarbonyl group  CH 3 -C-H In a ketone, two carbon groups are attached to a carbonyl group Ocarbonyl group  CH 3 -C-CH 3

Robert J. O'Reilly3 Naming Aldehydes IUPAC Replace the -e in the alkane name -al Common Add aldehyde to the prefixes form (1C), acet (2C), propion(3), and butry(4C) O O O    H-C-H CH 3 -C-HCH 3 CH 2 C-H methanal ethanal propanal (formaldehyde) (acetaldehyde) (propionaldehyde)

Robert J. O'Reilly4 Aldehydes as Flavorings

Robert J. O'Reilly5 Glucose is an aldehyde

Robert J. O'Reilly6 Naming Ketones In the IUPAC name, the -e in the alkane name is replaced with -one In the common name, add the word ketone after naming the alkyl groups attached to the carbonyl group O  CH 3 -C-CH 3 CH 3 -C-CH 2 -CH 3 Propanone 2-Butanone (Dimethyl ketone) (Ethyl methyl ketone)

Robert J. O'Reilly7 Ketones O O  Butter flavorCH 3 -C-C-CH 3 butanedione O  Clove flavorCH 3 -C-CH 2 CH 2 CH 2 CH 2 CH 3 2-heptanone

Robert J. O'Reilly8 Fructose is a Ketone

Robert J. O'Reilly9 Ketones as Hormones

Robert J. O'Reilly10 Learning Check AK 1 Classify each as an aldehyde (1), ketone (2) or neither(3). O  A. CH 3 CH 2 CCH 3 B. CH 3 -O-CH 3 CH 3 O  C. CH 3 -C-CH 2 CHD. CH 3

Robert J. O'Reilly11 Solution AK 1 Classify each as an aldehyde (1), ketone (2) or neither(3). O  A. CH 3 CH 2 CCH 3 2 B. CH 3 -O-CH 3 3 CH 3 O  C. CH 3 -C-CH 2 CH 1 D. 2 CH 3

Robert J. O'Reilly12 Learning Check AK 2 Name the following O  A. CH 3 CH 2 CCH 3 B. CH 3 O  C. CH 3 -C-CH 2 CH CH 3

Robert J. O'Reilly13 Solution AK 2 O  A. CH 3 CH 2 CCH 3 B. 2-butanone (ethyl methyl ketone) CH 3 O  C. CH 3 -C-CH 2 CH cyclohexanone CH 3 2,2-dimethylbutanal

Robert J. O'Reilly14 Learning Check AK 3 Draw the structural formulas for each: A. 3-Methylpentanal B. 2,3-Dichloropropanal C. 3-Methyl-2-butanone

Robert J. O'Reilly15 Solution AK 3 Draw the structural formulas for each: CH 3 O  A. 3-MethylpentanalCH 3 CHCHCH 2 CH Br O  B. 2,3-Dichloropropanal Br-CH 2 CHCH O  C. 3-Methyl-2-butanoneCH 3 CHCCH 3 CH 3