Shapes and Orientations of Orbitals. Periodic table arrangement the quantum theory helps to explain the structure of the periodic table. n - 1 indicates.

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Shapes and Orientations of Orbitals

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Presentation transcript:

Shapes and Orientations of Orbitals

Periodic table arrangement the quantum theory helps to explain the structure of the periodic table. n - 1 indicates that the d subshell in period 4 actually starts at 3 (4 - 1 = 3).

The location of electrons is described by: n, l, m l n = size, l = shape, m l = orientation

Electron clouds The “probability” of finding an electron around a nucleus can be calculated. Relative probability is indicated by a series of dots, indicating the “electron cloud”. 90% electron probability/cloud for 1s orbital (notice higher probability toward the centre)

p orbitals and d orbitals p orbitals look like a dumbell with 3 orientations: p x, p y, p z (“p sub z”). Four of the d orbitals resemble two dumbells in a clover shape. The last d orbital resembles a p orbital with a donut wrapped around the middle.

4s 3s 2s 1s 2p 3p 3d ENERGYENERGYENERGYENERGY n l mlml msms 10(s) 2 1(p) ,10, 30(s) 1(p) 0 -1,10, 2(d) -1,1,0, -2, 2 40(s)0 Movie: periodic table of the elements: t10-20