ENERGY SUPPORT Experts in providing mobile Solutions Energy Support GmbH. Sperberweg 47. D Neuss T F On – site Dissolved Gas Analysis according to IEC60567 / ASTM D 3612

ENERGY SUPPORT Experts in providing mobile Solutions Energy Support GmbH. Sperberweg 47. D Neuss T F Which tests can you do on transformer oil at – site? Breakdown voltage tests Tan Delta and resistivity tests Water content measurement acc. to Karl-Fischer Total gas content measurement Dissolved Gas analysis The total of all parameters allows a diagnostic about the condition of the transformer

ENERGY SUPPORT Experts in providing mobile Solutions Energy Support GmbH. Sperberweg 47. D Neuss T F What is Dissolved Gas Analysis? A quantitative analysis of all dissolved gases in the transformer oil. The analysis is done after the extraction of the gases and a gas chromatography thereafter. The aim of the analysis is an early determination of aging and functional problems of the transformer. 모든정량분석은 변압기 오일을 용해하는것입니다. 이 분석은 가스의 추출과 가스 chromatography thereafter 를 한후에 이루어 집니다. 이 분석의 목표는 변압기의 노화와 기능적결함을 초기에 진단하는 것입니다. PREDICTIVE MAINTENANCE !

ENERGY SUPPORT Experts in providing mobile Solutions Energy Support GmbH. Sperberweg 47. D Neuss T F Which gases need to be detected ? accord. to ASTM 3612 / IEC 567 ASTM 3612IEC 567 Oxygen O 2, Nitrogen N 2 Oxygen O2, Nitrogen N2 Hydrogen H 2 Hydrogen H2 Carbon Monoxid CO, Carbon Dioxid CO 2 Carbon Monoxid CO, Carbon Dioxid CO2 Methan CH 4 Methan CH4 Ethan C 2 H 6 Ethan C2H6 Ethylen C 2 H 4 Ethylen C2H4 Acetylen C 2 H 2 Acetylen C2H2 Propan C 3 H 8 (Propan C3H8, Propylen C3H6 Propylen C 3 H 6

ENERGY SUPPORT Experts in providing mobile Solutions Energy Support GmbH. Sperberweg 47. D Neuss T F Which gases are detected ? Oxygen O 2, Nitrogen N 2 Hydrogen H 2 Carbon Monoxid CO, Carbon Dioxid CO 2 Methan CH 4 Ethan C 2 H 6 Ethylen C 2 H 4 Acetylen C 2 H 2 Propan C 3 H 8 Propylen C 3 H 6

ENERGY SUPPORT Experts in providing mobile Solutions Energy Support GmbH. Sperberweg 47. D Neuss T F The Use of Atmospheric Gases N2 and O2 are indispensable for the evaluation of the transfomer condition N2: Referenzvalue for the gas saturation. O2: Very important indicator for the ageing process

ENERGY SUPPORT Experts in providing mobile Solutions Energy Support GmbH. Sperberweg 47. D Neuss T F N 2 H 2 Gas saturation level > < ppm

ENERGY SUPPORT Experts in providing mobile Solutions Energy Support GmbH. Sperberweg 47. D Neuss T F The Use of Secondary Gases (Propan and Propen) The ‘Memory‘ of Thermic Faults Due to the slow solubility of C3H6 and C3H8 both gases serve as a memory of Thermic faults.

ENERGY SUPPORT Experts in providing mobile Solutions Energy Support GmbH. Sperberweg 47. D Neuss T F Reasons for high gas content and interpretation of the values with ratios Electrical DischargeAcetylen C2H2  3 Ethan C2H6 Partial DischargeHydrogen H2  10 Methan CH4 Overheating of OilEthylen C2H4  1 for temperatures below 300 o C Propylen C3H6  1 for temperatures over 300 o C Overheating of cellulosisCarbondioxid CO2  10 Carbonmonoxid CO Degradation of cellulosis caused by electr. Faults Carbondioxid CO2  3 Carbonmonoxid CO Leakage, contamination of the oil with ambient airOxygen O2 Nitrogen N2 Leacking tap changer vesselAcetylen C2H2  2 Hydrogen H2

ENERGY SUPPORT Experts in providing mobile Solutions Energy Support GmbH. Sperberweg 47. D Neuss T F An Example of Premature Ageing

ENERGY SUPPORT Experts in providing mobile Solutions Energy Support GmbH. Sperberweg 47. D Neuss T F Advantages of on-site analysis Minimizing problems of oil sampling Time reduction ( sample dispatch, waiting for results ) Direct Buchholzgas analysis Short reaction times

ENERGY SUPPORT Experts in providing mobile Solutions Energy Support GmbH. Sperberweg 47. D Neuss T F Steps of the Dissolved Gas Analysis Degassing Gas chromatography Interpretation of the values with integrated expert - system

ENERGY SUPPORT Experts in providing mobile Solutions Energy Support GmbH. Sperberweg 47. D Neuss T F Degassing of oil sample 1. Preparation 2. Oilsample 3. Degassing 4. Gas transfer

1

2

3

4

ENERGY SUPPORT Experts in providing mobile Solutions Energy Support GmbH. Sperberweg 47. D Neuss T F Partial Vacuum degassing acc. to IEC EN Advantages: Easy extraction at-site Simple to handle Very high sensibility High accuracy Comparable with laboratory degassing

ENERGY SUPPORT Experts in providing mobile Solutions Energy Support GmbH. Sperberweg 47. D Neuss T F

ENERGY SUPPORT Experts in providing mobile Solutions Energy Support GmbH. Sperberweg 47. D Neuss T F

ENERGY SUPPORT Experts in providing mobile Solutions Energy Support GmbH. Sperberweg 47. D Neuss T F Principle of a gas chromatographic analysis Gas supply Flow- Controller Injection system Detector Column with oven Electronic amplifier Computer

ENERGY SUPPORT Experts in providing mobile Solutions Energy Support GmbH. Sperberweg 47. D Neuss T F Automatic sample Loop Sample Loop with fixed dosing: 100 µl Carrier gas Position „Load“ Position „Inject“

ENERGY SUPPORT Experts in providing mobile Solutions Energy Support GmbH. Sperberweg 47. D Neuss T F Schematic of the Gaschromatograph

ENERGY SUPPORT Experts in providing mobile Solutions Energy Support GmbH. Sperberweg 47. D Neuss T F Typical Chromatograms TCD-ChannelFID-Channel

ENERGY SUPPORT Experts in providing mobile Solutions Energy Support GmbH. Sperberweg 47. D Neuss T F MobilGC - Software Clearly structured with helpful tools for monitoring and evaluation

ENERGY SUPPORT Experts in providing mobile Solutions Energy Support GmbH. Sperberweg 47. D Neuss T F MobilGC - Evaluation Simple operation with clear structures

ENERGY SUPPORT Experts in providing mobile Solutions Energy Support GmbH. Sperberweg 47. D Neuss T F MobilGC – Expert- System

ENERGY SUPPORT Experts in providing mobile Solutions Energy Support GmbH. Sperberweg 47. D Neuss T F DUVAL TRIANGLE

ENERGY SUPPORT Experts in providing mobile Solutions Energy Support GmbH. Sperberweg 47. D Neuss T F Advantages of the MobilGC portable Gaschromatograph Internal gas supply Immediate analysis Direct analysis of Buchholzgases Online Monitoring of transformers through combination of autm. Vacuum degassing and MobilGC

ENERGY SUPPORT Experts in providing mobile Solutions Energy Support GmbH. Sperberweg 47. D Neuss T F Analyse und Probenvorbereitung entsprechen dem KYOTO – Protokoll  Flamme wird mit Wasserstoff betrieben  Es erfolgt keine Emission von CO2 in die Umgebungsluft

ENERGY SUPPORT Experts in providing mobile Solutions Energy Support GmbH. Sperberweg 47. D Neuss T F Automatic Vacuum Degassing without Mercury Patent Nr. DE

ENERGY SUPPORT Experts in providing mobile Solutions Energy Support GmbH. Sperberweg 47. D Neuss T F Automatic Vacuum Degassing without Mercury

ENERGY SUPPORT Experts in providing mobile Solutions Energy Support GmbH. Sperberweg 47. D Neuss T F Comparison Measurements Component Toepler-Pump Vacuum Degassing Lab GC Mobil GC Lab GC Mobil GC H2H CO CO Methan Ethan Ethylen10,110,07,410,9 Acetylen0,81,00,40,76

Features and Benefits: ■ Fully automatic procedure ■ One touch operation ■ Multi-periodic vacuum degassing ■ Fast and reliable ■ Full TOGA analysis ( 11 gases ) ■ Automatic transfer of gas sample ■ Compl. to ASTM3612 / IEC 567 ENERGY SUPPORT Experts in providing mobile Solutions Energy Support GmbH. Sperberweg 47. D Neuss T F TOP-TOGA- GC

Automatic Vacuumdegassing without Mercury Short degassing time ( < 3 min.) Automatic Transfer of the gases to the GC Additional analog ports for further parameters Plausibility test and trendanalysis ENERGY SUPPORT Experts in providing mobile Solutions Energy Support GmbH. Sperberweg 47. D Neuss T F Online-Monitoring with Automatic Vacuumdegassing and MobilGC

ENERGY SUPPORT Experts in providing mobile Solutions Energy Support GmbH. Sperberweg 47. D Neuss T F Further products for transformer testing Karl Fischer Pocket Titrator Tan delta and Resistivity Measurement Total Gas Content Measurement Capacitance test on transfomers Petrochemical and Environmental Applications

ENERGY SUPPORT Experts in providing mobile Solutions Energy Support GmbH. Sperberweg 47. D Neuss T F Pocket Titrator Low background drift measuring cell Preconfigured methods “One click” measurement AEC (automatically electrolysis controlled) High precision even in low concentrations Suitable for all commonly used Karl-Fischer- reagents

ENERGY SUPPORT Experts in providing mobile Solutions Energy Support GmbH. Sperberweg 47. D Neuss T F Tan Delta and Resistivity Measurement Fully automatic testing sequence Optional manual testing sequence Automatic calibration and resistance measurement Windows software Menu driven software operations

ENERGY SUPPORT Experts in providing mobile Solutions Energy Support GmbH. Sperberweg 47. D Neuss T F Total Gas Content Measurement Gas separation by means of fully vacuum degassing ( accord. to DIN EN 60567, DIN IEC 599 and IEEE C ) and display of results Subsequently to the determination of the total gas content a gas chromatographic analysis can be made.

ENERGY SUPPORT Experts in providing mobile Solutions Energy Support GmbH. Sperberweg 47. D Neuss T F Petrochemical and Environmetal Applications portable GC for various applications H 2 S Analysis LPG Analysis Environmental Applications

ENERGY SUPPORT Experts in providing mobile Solutions Energy Support GmbH. Sperberweg 47. D Neuss T F Thank you for your attention ! MODERN-INTEC T