Introduction to Organic Chemistry:
Largest Chemistry Field in the Modern World Medicines Plastics Synthetics Fuels
Carbon Forms 4 Strong Covalent Bonds Makes countless combinations of molecules all based on Carbon Must NAME them carefully to allow others to reproduce them
1. Meth- 2. Eth- 3. Prop- 4. But- 5. Pent- 6. Hex- 7. Hept- 8. Oct- 9. Non- 10. Dec- # of Carbons
We start with the simplest type of organic molecule Alkane Saturated Hydrocarbons ▪ Maximum amount of Hydrogens Only Single Bonds between Carbons
1. Work Backwards 2. Start with the ending –ane means “Only Single Bonds” 3. Find longest unbroken line of carbons. This stem determines the prefix. (meth-, eth-, etc)
4. Circle all carbon groups not on the stem, these are branches 5. Name them using the same prefixes, but an –yl ending 1 Carbons = Methyl, 2 Carbons = Ethyl 3 Carbons = Propyl, 4 Carbons = Butyl
6. Arrange branches alphabetically 7. Add extra prefixes if there are multiple of the same branch instead of rewriting them. 2 of same = Di, 3 of same = Tri Ex: dimethyl = 2 branches w/ 1 carbon each
8. Number the carbons on the stem Start at the end closest to a branch 9. Record the # of the attached stem carbon next to each branch These numbers are addresses, explaining where a branch is on the stem (location, not amount)
6 : Arrange Branches Alphabetically ethylmethyl octane 7 : Extra Prefixes (di & tri) ethyl dimethyl octane 8 : Number Carbons (near branch) ethyl dimethyl octane : Label branches (use stem address) 4-ethyl 3,5-dimethyl octane 1&2 : Start Backwards, -ane ending -ane 3 : Find Stem (Longest Line of C) octane 4 : Circle Branches (C not on Stem) octane 5 : Name Branches (prefix-yl) octane Methyl Ethyl 4 Carbons 3 Carbons
4-ethyl 3,5-dimethyl octane It is all about Decoding the Name. This is why the name must be carefully constructed.
5 C 6 C6 C 6 C6 C 8 C8 C 8 C8 C Either of these works, and have same name
Click for Answer 2,5-dimethyl octane
,5,6-trimethyl nonane Click for Answer
ethyl 2,3,3-trimethyl hexane
Click for Answer 7,8-diethyl 2,3,6-trimethyl decane
Make your life easy! Straight Stem starting at #1 2,2,6-trimethyl heptane Notice: each C has 4 Bonds when finished. Lines + H = 4 for each C #1 #2 #3 #4 #5 #6 #7