1 WLTP Open Issue Phase 1B Issue: Definition of NMHC & THC density. ACEA Informal Document 04.03.2014 WLTP-06-18e.

Slides:



Advertisements
Similar presentations
1 WLTP Open Issue Phase 1B Issue: Generic formula for hydrocarbon density. ACEA Informal Document WLTP rev1e.
Advertisements

Deptt. Of Applied Sciences Govt. Polytechnic College For Girls Patiala Presented By- Dr. Raman Rani Mittal M.Sc., M.Phil, Ph.D. (Chemistry) 1.
Molar Quantities: Balancing Equations
Molecular Compostion of Gases
Moles, volume and density
1 WLTP Open Issue Phase 1B Issue: Petrol Tank Inlet Orifice. ACEA Informal Document WLTP-06-09e.
1 WLTP Open Issue Phase 1B Issue: Generic formula for total hydrocarbon density. ACEA Informal Document WLTP-07-11e.
Unit 5 CHEMICAL QUANTITIES CHAPTER 10 – THE MOLE.
HIGHER GRADE CHEMISTRY CALCULATIONS Molar Volume. The molar volume is the volume occupied by one mole of a gas. Worked example 1. In an experiment the.
NOTES: 10.3 – Empirical and Molecular Formulas What Could It Be?
The Mole – A measurement of matter
Chemical Stoichiometry Reacting Quantities and Material Balance Edward A. Mottel Department of Chemistry Rose-Hulman Institute of Technology.
Using the Ideal Gas Law and Previously Learned Concepts
Chemistry Notes Empirical & Molecular Formulas. Empirical Formula The empirical formula gives you the lowest, whole number ratio of elements in the compound.
Molar volume Text Book : Pages SPECIFICATIONS.
1 WLTP Open Issue Phase 1B Issue: Amendment of OIL#42 - Willans factors for petrol (E10) & diesel (B7). ACEA Informal Document WLTP rev1e.
1 WLTP Open Issue Phase 1B Issue: Fuel Consumption calculations for ICE vehicles. ACEA Informal Document WLTP-08-07e.
Chapter 2Stoichiometry Stoichiometry: the science dealing with quantitative relationships involving the mass of substances and the number of particles.
The Mole & Chemical Formulas A chemical formula represents the ratio of atoms that always exists for that compound Example: Water – H 2 O Always 2 H atoms.
Molecular Formulas 1.Find empirical formula 2.Calculate molar mass of empirical formula 3.Molar mass of compound / molar mass of empirical formula (we’ll.
Empirical Formulas & Molecular Formulas Empirical Formulas Molecular Formulas.
Empirical and Molecular Formulas
Percent Composition, Empirical Formulas, Molecular Formulas
Chemical Quantities.  Calculate the mass of compounds.  Calculate the molar volumes of gases.  Solve problems requiring conversions between mass, and.
1 WLTP Open Issue Phase 1B Issue: Generic formula for hydrocarbon density. JAPAN Informal Document WLTP-07-12e.
The Mole: A Measurement of Matter
Chapter 10: Chemical Quantities
The Mole: A measurement of Matter
Chapter 7 The Mole: A Measurement of Matter
Gases Chapter 10/11 Modern Chemistry
Combustion Analysis Topic #13
A MOLE IS JUST A NUMBER 6.02 X Mole. Mole Map.
5.5 Molecular Formula Percent Composition. Review of Empirical Formula.
The Mole 1 dozen = 12 1 gross = ream = mole = 6.02 x 1023.
Percentage Composition: is the percent mass of each element present in a compound.
What Could It Be? Empirical Formulas The empirical formula is the simplest whole number ratio of the atoms of each element in a compound. Note: it is.
Percent Composition Empirical & Molecular Formulas.
Mole Calculations. The Mole Mole – measurement of the amount of a substance. –We know the amount of different substances in one mole of that substance.
THE MOLE Chapter 10: Chemical Quantities Measuring Matter What is a mole? It is the SI unit that measures the amount of substance.
Empirical and Molecular Formulas. Caffeine is 49.48% C, 5.15% H, 28.87% N and 16.49% O. What is its empirical formula? Empirical Mass=
AEGPL amendments proposals to Regulations n. 83 and 115 Bi-fuel vehicles – New definition and provisions GFV - Brussels, 15 th December 2011.
1 WLTP Open Issue Phase 1B Issue: Fuel Consumption interpolation method. ACEA Informal Document WLTP-08-08e.
1 WLTP Open Issue Phase 1B Issue: Handling of Manual Mode with Automatic Transmission. ACEA Informal Document WLTP-06-17e.
Gas Density The density of gases is much less than that of liquids.
Empirical and Molecular Formulas. Formulas  molecular formula = (empirical formula) n  molecular formula = C 6 H 6 = (CH) 6  empirical formula = CH.
Unit 1 Gases. Ideal Gases Objectives 1. Compute the value of an unknown using the ideal gas law. 2. Compare and contrast real and ideal gases.
Calculating Empirical and Molecular Formulas. Calculating empirical formula A compound contains 79.80% carbon and 20.20% hydrogen. What is the empirical.
Molecular Formulas. An empirical formula shows the lowest whole-number ratio of the elements in a compound, but may not be the actual formula for the.
UNIT 6: CHEMICAL QUANTITIES Chapter 10: Mole and Volume Relationships.
Section 6.2 Molar Mass and Percent Composition 1.To understand the definition of molar mass 2.To learn to convert between moles and mass 3.To learn to.
1 Percent Composition: Identifies the elements present in a compound as a mass percent of the total compound mass. The mass percent is obtained by dividing.
Calculating Empirical Formulas
Determining Empirical Formula from Combustion Analysis 1.
The Mole Honors Chem. -How do we measure chemical quantities? -What units of measure do we use?
1 Chapter 7 Chemistry Empirical Formulas/molecular formulas LOOK AT: Pages
Chapter 7 Moles. What is a Representative Particle The smallest unit into which a substance can be broken down without changing the composition of the.
Chemical Quantities Chapter 10. The Mole  a mole is an amount of matter  mass is also an amount of matter, however the mole is much more useful to chemists,
Quantitative chemistry
IMMA proposal for GTR2 B2 on NMHC and CFV
Empirical formula – the chemical formula of a compound written using the smallest, whole number, mole ratio between atoms in the compound. What is the.
IDEAL GAS LAW.
% Formula Mass and % Composition
7.5 – NOTES Molecular Formulas
Combustion Analysis The composition of a substance is often determined by using a specified reaction to break down the substance into known measurable.
Ch. 7-3 Percent Composition
Percentage Composition
Empirical and Molecular Formulas
7.3 – NOTES Molecular Formulas
Reading Guide 10.3b Empirical Formulas Molecular Formulas
GTR Corrections, Open Points, Expert Proposals and Confirmations in GTR 15 8/13/2019.
Presentation transcript:

1 WLTP Open Issue Phase 1B Issue: Definition of NMHC & THC density. ACEA Informal Document WLTP-06-18e

2 Current Text of WLTP gtr The mass of gaseous compounds emitted by the vehicle during the test shall be determined by obtaining the product of the volumetric concentration of the gas in question and the volume of the diluted exhaust gas with due regard for the following densities under the reference conditions of K and kPa: Carbon monoxide (CO) ρ = 1.25 g/l Carbon dioxide (CO 2 ) ρ = g/l... Page 2

3 Current Text of WLTP gtr Hydrocarbons: for petrol (E0) (C 1 H 1.85 ) ρ = g/l for petrol (E5) (C 1 H 1.89 O ρ = g/l for diesel (B0) (C 1 H 1.86 ) ρ = g/l for diesel (B5) (C 1 H 1.86 O ) ρ = g/l for LPG (C 1 H ) ρ = g/l for NG/biomethane (CH 4 ) ρ = g/l for ethanol (E85) (C 1 H 2.74 O ) ρ = g/l The density for NMHC mass calculations shall be equal to that of total hydrocarbons at K and kPa and is fuel-dependent. Page 3

4 Proposal: A generic formula for the density of total hydrocarbons and non- methane hydrocarbons respectively should be added. The ratios of H/C and O/C for reference fuels shall be taken from Annex 3. These numbers have to be added to the actual draft. The density shall be rounded to three decimal places. Rationale: The density of total hydrocarbons (HC) and non-methane hydrocarbons (NMHC) of different types of fuel differ due to varying H/C and O/C ratios. This approach supports the simple adaption to future reference fuels or changes to the existing ones. A generic formula in combination with the nomination of the H/C and O/C ratios in Annex 3 results in clarification and standardization of the density values. This approach can also be the base for the calculation of the fuel consumption in Annex 7.6. Page 4

5 Generic formula: ρ HC/NMHC : density of total hydrocarbons and non-methane hydrocarbons [g/l] MW C : molecular weight of carbon = g/mol MW H : molecular weight of hydrogen = g/mol MW O : molecular weight of oxygen = g/mol V M : molar volume for an ideal gas at 0°C and kPa = l/mol H/C: ratio of hydrogen to carbon for a specific fuel C x H y O z O/C: ratio of oxygen to carbon for a specific fuel C x H y O z Page 5

6 Generic formula with physical constants: Example petrol E(5): C 1 H 1.89 O Page 6