Homework Answers 10.31 – Constant T so P vap is constant at 28.0 mm Hg 10.47 – a) melting, b) no change, still liquid 10.49 – boils when P atm gets down.

Slides:



Advertisements
Similar presentations
Intermolecular Forces, Liquids and Solids
Advertisements

Materials Science and Engineering Crystalline and Non-Crystalline Systems X-Ray Diffraction: Determination of Crystal Structure.
4. Investigations into the electrical properties of particular metals at different temperatures led to the identification of superconductivity and the.
Solids Image:Wikimedia Commons User Alchemistry-hp.
Homework Answers – a) cubic-closest, b) simple cubic, c) hex.-closest, d) body-centered cubic – a) CaTiO 3, b) – a) 175 pm, b) 11.3.
Figure 16.9: Three cubic unit cells and the corresponding lattices.
Solid State Physics 2. X-ray Diffraction 4/15/2017.
Sections 12.1 – 12.2 Types of Solids Metallic Solids Bill Vining SUNY Oneonta.
Solids crystalline amorphous well defined structures no orderly structure glass quartz SiO 2 crystal latticesystem of points describes arrangement of particles.
Solids Classified into two general types: a.Crystalline b.amorphorous.
THE NATURE OF SOLIDS SECTION 10.3 After reading Section 10.3, you should know: properties of solids the difference between single-cubic, body- centered.
Dr. S. M. Condren Chapter 15 The Liquid State, The Solid State, and Modern Materials.
Chapter 2. Reciprocal Lattice Issues that are addressed in this chapter include: - Reciprocal Lattice - Packing Factor - Bragg law - Scattered wave amplitude.
Structures of Solids. Glass (SiO 2 ) Crystal Noncrystal Solid.
Crystal Structure: Cubic System (BCC, FCC)
Chapter 12 Intermolecular Forces and the Physical Properties of Liquids and Solids Insert picture from First page of chapter Copyright McGraw-Hill 2009.
Chapter 12: Solids. Types of Solids: Ionic Molecular Network: crystalline amorphous Metallic.
Crystalline Structures Edward A. Mottel Department of Chemistry Rose-Hulman Institute of Technology.
Crystalline Structures Edward A. Mottel Department of Chemistry Rose-Hulman Institute of Technology.
CHE (Structural Inorganic Chemistry) X-ray Diffraction & Crystallography lecture 2 Dr Rob Jackson LJ1.16,
Copyright©2000 by Houghton Mifflin Company. All rights reserved. 1 Figure 10.1 Schematic Representations of the Three States of Matter.
Copyright©2000 by Houghton Mifflin Company. All rights reserved. 1 Intermolecular Forces Forces between (rather than within) molecules.  dipole-dipole.
Chapter 10 Liquids & Solids
Chapter 13 States of Matter 13.3 The Nature of Solids
Liquids, Solids, and Phase Changes
Copyright©2000 by Houghton Mifflin Company. All rights reserved. 1 Chemistry FIFTH EDITION Chapter 10 Liquids and Solids.
1 Unit 2 - Crystallography In most solids, atoms fit into a regular 3-dimensional pattern called a crystal In most solids, atoms fit into a regular 3-dimensional.
Properties of Solids. Copyright © Pearson Education, Inc., or its affiliates. All Rights Reserved. What is the strongest material in the world? CHEMISTRY.
Phase Changes (i.e., changes of state) -- energy changes required are related to IMFs -- melting, freezing, boiling (vaporization), condensation, sublimation,
States of Matter; Liquids and Solids
John E. McMurry Robert C. Fay Lecture Notes Alan D. Earhart Southeast Community College Lincoln, NE General Chemistry: Atoms First Chapter 10 Liquids,
Chapter 10 Liquids and Solids Intermolecular Forces Forces between (rather than within) molecules.  dipole-dipole attraction: molecules with dipoles orient.
1 Structures of Solids n Solids have maximum intermolecular forces. n Molecular crystals are formed by close packing of the molecules (model by packing.
Logarithm Review ab = c, (a > 0, a ≠ 1) logac = b log c = log10c
Review of Chapter 10 (condensed states of matter) A.P. Chem Pressure→ Temperature→ SOLID Defined: Structural units held together by attractive forces enough.
Theory of diffraction Peter Ballo.
Copyright © 2011 Pearson Education, Inc. Publishing as Prentice Hall. Chapter 6 Geometry.
Crystal Structures & X-ray Diffraction Chemistry 123 Spring 2008 Dr. Woodward.
Ionic bonding between sodium and chlorine atoms. Electron transfer from Na to Cl creates a cation (Na + ) and an anion (Cl − ). The ionic bond is due to.
Crystalline Solids BLB 12 th Chapter 12 Sections 1-3, 5.
Copyright © 2012 Pearson Education, Inc. Publishing as Prentice Hall. Section 1.3 Complex Numbers Quadratic Equations in the Complex Number System.
1 Solids. 2 Structures of Solids Crystalline vs. Amorphous Crystalline solid: well-ordered, definite arrangements of molecules, atoms or ions. –Most solids.
Liquids & Solids Dr. Ron Rusay Fall States of Matter.
An Introduction to Structures and Types of Solids
Engineering Chemistry Copyright  2011 Wiley India Pvt. Ltd. All rights reserved.
Sections 12.1 – 12.2 Types of Solids Metallic Solids.
Prentice Hall © 2003Chapter 11 Types of Solids Molecular Solidsex. CO 2, H 2 O, Ar Covalent-Network Solidsex. Diamond, quartz, SiO 2 Metallic Solidsex.
Vapor Pressure and Boiling Point Liquids boil when the external pressure equals the vapor pressure. Temperature of boiling point increases as pressure.
UNIT CELL – The smallest repeating unit of a crystalline solid EXP11-1 (of 11) UNIT CELLS.
Solids Image:Wikimedia Commons User Alchemistry-hp.
Chapter 10 Problem The melting point of potassium is 63.2 o C. Molten potassium has a vapor pressure of 10.0 torr at 443 o C and a vapor pressure of
8–1 CHM 105 LECTURE NOTE States of Matter; Liquids and Solids BY DR. J.J.GONGDEN’
Crystal Structure and Crystallography of Materials Chapter 14: Diffraction Lecture No. 2.
Section 2.4 Circles Copyright © 2012 Pearson Education, Inc. Publishing as Prentice Hall.
Section 8.3 The Law of Cosines
Copyright © 2008 Pearson Prentice Hall Inc.
Copyright © 2008 Pearson Prentice Hall Inc.
Mathematical Models: Building Functions
Copyright © 2008 Pearson Prentice Hall Inc.
Copyright © 2008 Pearson Prentice Hall Inc.
Chapter 12 Unit Cells.
Partial Fraction Decomposition
UNIT CELLS UNIT CELL – The smallest repeating unit of a crystalline solid EXP11-1 (of 11)
Quadratic Equations in the Complex Number System
Copyright©2000 by Houghton Mifflin Company. All rights reserved.
Partial Fraction Decomposition
Properties of Rational Functions
Copyright © 2008 Pearson Prentice Hall Inc.
Copyright © 2008 Pearson Prentice Hall Inc.
Presentation transcript:

Homework Answers – Constant T so P vap is constant at 28.0 mm Hg – a) melting, b) no change, still liquid – boils when P atm gets down to P vap – 36.6 kJ released – 26.9 kJ released – – 7.12 J/(K∙mole) – BP = 77˚C, Pvap = 58.9 mm Hg Copyright © 2008 Pearson Prentice Hall, Inc.Chapter 1/1

Unit Cells in Crystalline Solids Copyright © 2008 Pearson Prentice Hall, Inc.

Chapter 10/6 Probing the Structure of Solids: X-Ray Crystallography Diffraction: Occurs when electromagnetic radiation is scattered by an object containing regularly spaced lines (such as a diffraction grating) or points (such as the atoms in a crystal). Interference: Occurs when two waves pass through the same region of space.

Copyright © 2008 Pearson Prentice Hall, Inc.Chapter 10/7 Probing the Structure of Solids: X-Ray Crystallography Bragg Equation: d = 2 sin  n

ATP by X-ray diffraction

Copyright © 2008 Pearson Prentice Hall, Inc.Chapter 10/11 Unit Cells and the Packing of Spheres in Crystalline Solids Body-Centered Cubic Packing Simple Cubic Packing

Copyright © 2008 Pearson Prentice Hall, Inc.Chapter 10/14 Unit Cells and the Packing of Spheres in Crystalline Solids Cubic Closest- Packing Hexagonal Closest- Packing

Copyright © 2008 Pearson Prentice Hall, Inc.Chapter 10/15 Unit Cells and the Packing of Spheres in Crystalline Solids Unit Cell: A small repeating unit that makes up a crystal.

Primitive cubic unit cell

Body-centered cubic unit cell

Body-centered cubic unit cell Primitive cubic unit cell

Face-centered cubic unit cell

Structures of Some Ionic Solids

H46 – C – 10.16, 10.23, 10.25,10.73 – 10.77(odd), 10.79*, 10.83*, , *