Copyright 2009 Chemithon Enterprises Next Generation Oleochemical & Surfactant Technologies for 100th AOCS Meeting Orlando May 09.

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Presentation transcript:

Copyright 2009 Chemithon Enterprises Next Generation Oleochemical & Surfactant Technologies for 100th AOCS Meeting Orlando May 09

Copyright 2009 Chemithon Enterprises Green Technologies from the Global Sulfonation Leader The Chemithon Corporation

Copyright 2009 Chemithon Enterprises Value Adders from BioDiesel Methyl Ester Sulfonate (MES) Methyl Ester Ethoxylate (MEE)

Copyright 2009 Chemithon Enterprises Reduction of 1,4-Dioxane Dioxane Reduction Process

Copyright 2009 Chemithon Enterprises Environmental Technologies Flue Gas Conditioning DeNox Systems

Copyright 2009 Chemithon Enterprises FRACTIONATION

Palm Oil Based Oleochemicals Objectives  Sustainable value creation from palm oil  Independent platforms ─Food (Palmolein) ─Fuel (Biodiesel – C18 rich) ─Detergents (C12-14 & C16 Esters)  Based on renewable resource  Environmentally friendly product

Copyright 2009 Chemithon Enterprises Mass Balance RBD PS Transesterification Distillation Glycerine 185 MT 18 MT Fatty Acid Methyl Ester (FAME) MT C12-14 ME C16 ME C18 ME 2.5 MT 110 MT 71 MT

Copyright 2009 Chemithon Enterprises Product Specification Specifications C12/C14 Stream from 1 st column top :C14= 87 % & C12= 8 % C16 Methyl esters from 2 nd column top:C16= 99 % C18 Methyl esters from 3 rd column top:C18= 96.5%

Copyright 2009 Chemithon Enterprises HYDROGENATION

Fractionated C16 ME: C16 ME =99% IV=2.0 units max Moisture=500 ppm FFA=0.1% max Glycerol =0.1% max Hydrogenated C16 ME: C16= 99% IV = 0.1 Ni content = less than 10 ppm

Copyright 2009 Chemithon Enterprises C16 ME Hydrogenation Saturated C16 ME Ethoxylation Methyl Ester Ethoxylate (MEE) EO Sulfonation/SO 3 Methyl Ester Sulfonate (MES) EO: Ethylene Oxide ME: Methyl Ester HPC Products Detergents Based on Fraction C16 ME

Copyright 2009 Chemithon Enterprises Cont. Fixed Bed Hydrogenation Plant (Supplied to Carotino, Malaysia, 2008)

Copyright 2009 Chemithon Enterprises Oleochemicals Based on Fraction C18 ME C18 ME Epoxidation Epoxy C18 ME Bio-Polyol Per formic acid (H 2 O 2 +HCOOH) MEG/BF3 Bio-Diesel Synthesis of Polyurethane Compliant with EN Standard Blending of Bio-Polyol+Petrochemical- based polyols and isocynate Rigid Polyurethane Foam Wood like appearance, impervious to moisture, dimensionally stable Potential application-decorative or structural No nutritional value to insects and does not shrink, rot or decay

Copyright 2009 Chemithon Enterprises Advantages of the Project  Integrated complex with maximum value addition  Sustainability using renewable raw materials  Independent revenue platforms ─Food (Palmolein) ─Fuel (Biodiesel – C18 rich) ─Detergents (C12-14, C16 & C18 Esters)  Glycerin (pharma grade)  MES in dry flakes form - convenience of use  Biodiesel EN compliant (winter grade)

Copyright 2009 Chemithon Enterprises Fractional Distillation Palm oil methyl ester feed - C12-C14, C16, & C18 ME  After degassing  Distilled under vacuum  Continuous 3-column series distillation unit  Designed & engineered by Chemithon  Meets EN14214 norms for biodiesel

Copyright 2009 Chemithon Enterprises Hydrogenation Pure C16 Methyl Ester fraction containing about 0.1% C16:1 Methyl Ester after degassing  Hydrogenating in a trickle bed reactor  25 Bar(a) (max) & reactor temp of 200 °C  Full set of safety features

Copyright 2009 Chemithon Enterprises Global Reach Operating Companies  Beijing, Mumbai, Seattle, and Singapore Partners in  Milan/Busto Arsizio and Tokyo Manufacturing in  Busto Arsizio, Mumbai, Seattle, and Singapore