New Directions towards 10% Efficient Dye Solar Cells at 3GSolar Jonathan Goldstein IFCBC, 26 January 2011.

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Presentation transcript:

New Directions towards 10% Efficient Dye Solar Cells at 3GSolar Jonathan Goldstein IFCBC, 26 January 2011

Company Changes -New ownership and direction – from September Investment by private equity fund (Solar Partnership) advised by Smedvig Capital (UK) -Company located in Jerusalem; Staff of 12 -3GSolar has 13 background patents and licensing agreements with partners Bar Ilan University, Weizmann Institute and Joma International (Norway) 2

Background to Dye Solar Cell Technology 3 -Dye Solar Cells (DSC) first discovered by Prof. Michael Graetzel, Switzerland -Light conversion mechanism and materials completely different from conventional inorganic semiconductor (Si, CdTe, CuInSe 2 ) solar cells -Not based on microelectronics processing -Low cost materials -Very low-cost manufacturing - Main barrier for market entry to date is low efficiency -3GSolar identified a viable and experimentally verified route for higher efficiencies -Focus is incorporating this new approach into 3GSolar existing technology platform

4 3GSolar Photovoltaics – DSC Advantages Pilot Production at 3GSolar Belt Furnace Screen Printer Low Manufacturing Costs Main Manufacturing Processes – Screen Printing – Sintering Advantages – No high vacuum processing – No severe clean room conditions – No toxic chemicals

We are eliminating platinum in the carbon cathode 5

We have developed an in-house immobilized electrolyte 6

Our square cell design (external area 225 sq cm, aperture 202 sq cm) for pilot production 7

Large Area 3GSolar DSC (area 225 sq cm) with 5.4% efficiency at one sun-Confirmed by ECN, Holland 8

3GSolar Cell Endurance Tests 9

Captures more total light than Si – Sunny and cloudy days – Less sensitive to temperature than Si – Less sensitive to orientation than Si – Not sensitive to shading Results in lower $/kW-hr 3GSolar Photovoltaics – DSC Advantages 3GSolar Results May 2009

11 3GSolar Photovoltaics – Program Goal To achieve 10+% module efficiency in a printed solar cell Methodology Incorporating Foerster Resonance Energy Transfer (FRET) technology into the existing 3GSolar printed DSC platform Expected results Printed DSC – Low cost, high efficiency, long lifetime! Will result in 3GSolar entry into commercial, on-grid PV market

12 3GSolar Project Partners FP7 Prof. GraetzelProf. Torres Merck ECIC (Taiwan) Solaronix (Swiss) Torrey Hills (USA) Arie Zaban, BIU Dan Oron, Weizmann David Cahen, Weizmann Joma International, Norway 3GSolar Direct R&D Partners Collaboration

Current barrier Efficiency of 3GSolar commercial-size cell currently 5.4% The 3GSolar solution to boost efficiency – – FRET allows us to capture more of the solar spectrum Current 3GSolar current density is 12 mA/cm 2 vs. 24 mA/cm 2 expected for light capture to 900 nm Doubling light capture and increasing voltage leads to X2.5 previous efficiency Current best dye cell research lab results at 12% efficiency without FRET – FRET physics completely compatible with current 3GSolar module design (Plug and Play) 13 3GSolar Photovoltaics – problem and solution

14 FRET process is nonradiative Energy transfer from excited fluorophore (donor) to another chromophore (acceptor). D A Energy transfer Advantage of FRET is light absorption and electron injection roles are separated. Antenna molecules collect photons to feed to dye molecules. What is FRET?

15 COMPONENTFRET-DSCPHOTOSYNTHESIS Antenna – FRET DonorQuantum DotsChlorophylls FRET Acceptor & e - DonorDyeLH-II and LH-I Electron AcceptorTiO 2 Chemical Reaction Center Electron DonorI-I- Organic molecules (quinones) Photosynthesis achieves FRET efficiencies as high as 90%! QD dye FRET Process e - Injection TiO 2 e - Acceptor Light in e - Injection Chlorophyll Antenna Light in 1 Reactive Center 32 FRET and Photosynthesis

16 FRET – the performance potential Standard 3GSolar 650 nm FRET cell with I - electrolyte, 900 nm FRET cell with solid electrolyte, 900 nm Potential Current, mA/cm % IPCE, mA/cm Voltage, V0.7 >0.9 Fill Factor70% Efficiency5.9%11.8%>15.1% Typical 3GSolar IPCE Curve

Incident photon conversion spectra on three different electrode structures: – nc-TiO 2 /QD/a-TiO 2 – nc-TiO 2 /a-TiO 2 /dye – nc-TiO 2 /QD/a-TiO 2 /dye Combining QDs and dyes in FRET process dramatically increases photon conversion over whole visible spectrum Shifting dye absorption to longer wavelengths will further increase conversion 17 Work from lab of Prof. A. Zaban, BIU FRET Proof of Concept

Low manufacturing costs – Screen printing vs high vacuum for Si and thin film – Under $0.40/W peak module production costs – Lowest PV plant capital costs 18 3GSolar Photovoltaics – DSC Advantages

3GSolar is the leading developer of DSC technology The project will focus on incorporating FRET approach into 3GSolar’s DSC technology platform Will achieve 10+% efficiency in commercial scale printed modules DSC has very strong cost and technical advantages over existing Si and thin-film technologies 3GSolar will be a game-changer for the on-grid PV market Low capex and simple manufacturing lines allow installing plant sites anywhere in Israel or elsewhere on the globe 19 Summary