Post-Combustion CO 2 Capture using Solid Sorbents Sharon Sjostrom, Chief Technology Officer CREA Energy Innovations Summit, October 27, 2014 Carbon Capture:

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Post-Combustion CO 2 Capture using Solid Sorbents Sharon Sjostrom, Chief Technology Officer CREA Energy Innovations Summit, October 27, 2014 Carbon Capture: Around the Corner or Around the Bend?

Phase I: Concept Phase II: Pilot Testing (1 MW) Phase III: Demonstration (> 25 MW) Commercial Implementation Development Approach ► Begin with the end in mind ► Identify cost drivers ► Focus R&D and execute work schedule with commercialization goal in mind DE-FE © 2014 ADA-ES, Inc. All Rights Reserved

Post-Combustion CO 2 Capture Emission Control SO 2, NO x, Hg, Particulate STEAM WATER Coal* 50% C 20% H 2 O 12% O 2 5% Ash 3% H 2 (S, Hg) * Coal composition varies greatly with grade and source. CO 2 Capture Air 78% N 2 21% O 2 Purified CO 2 to Storage/EOR/etc. Regeneration Flue Gas 12% CO 2 74% N 2 12% H 2 O 4% O 2 CO 2 Solids functionalized with amines react with CO 2 at “low” temperatures Solids are heated to reverse reaction with CO 2 Temperature swing adsorption (TSA) Solids functionalized with amines react with CO 2 at “low” temperatures Solids are heated to reverse reaction with CO 2 Temperature swing adsorption (TSA) © 2014 ADA-ES, Inc. All Rights Reserved

► Flue gas passes through adsorber module where sorbent particle adsorbs CO 2 ► Regenerable solid sorbent cycles between adsorber and regenerator. ► Increased temperature in regenerator releases CO 2 Flue Gas Flue Gas Preparation CO 2 Adsorber Baghouse Regenerator BaghouseCO 2 Compression CO 2 Storage Flue Gas CO 2 Solid Sorbent Heat Exchanger Process Blower ADAsorb™ Process Flue Gas CO 2 Sorbent Patent Pending Design © 2014 ADA-ES, Inc. All Rights Reserved

Pilot Construction Activities ► Pilot designed in “modules” ► Off-site fabrication © 2014 ADA-ES, Inc. All Rights Reserved

Pilot Module Transport © 2013 ADA-ES, Inc. All Rights Reserved

Construction at Southern Company Host Site © 2014 ADA-ES, Inc. All Rights Reserved

Process Validation through Pilot Testing Phase II Progress ► System Design: 2012 ► Pilot Construction: 2013 ► Sorbent Prep and Testing: ► Testing: D Process Model © 2014 ADA-ES, Inc. All Rights Reserved

Stantec Consulting, Ltd. o Cost Analysis, Plant Integration Owners Engineer Perspective McAbee Construction Pilot fab and installation EPRI o Technical Advisor o Cost Share o Independent Performance Evaluation and Techno- Economic Assessment Southern Company o Host Site, Cost Share Luminant o Cost Share DOE – NETL o Project Sponsor ADA-ES, Inc. o Project Management o Developed Process Concept o Sorbent Eval & Selection o Process Validation Testing o Techno-Economic Assessment o Cost Share Technip Stone and Webster Process Technology o Detailed Engineering Services Significant Experience with Fluidized Bed Reactor Design Project Team © 2014 ADA-ES, Inc. All Rights Reserved

Is CO 2 Capture Around the Corner, or Around the Bend? ► Post-combustion controls must be included in any plan for significant CO 2 reductions ► Current regulatory landscape is slowing development Proposed GHG regulations for new plants and cost of gas in US restricts development Proposed regulations for existing plants do not present a clear commercial market for controls ► Will final regulations and oil prices support use of fossil-generated CO 2 ? © 2014 ADA-ES, Inc. All Rights Reserved

Thank You Sharon Sjostrom CTO © 2014 ADA-ES, Inc. All Rights Reserved