Slides 2-4: Agust,www,....rempi/hcl/October08/HClg3S-V9V10-311008ak.ppt & Agust,www,....rempi/hcl/October08/HClg3S-V9V10-031108ak.ppt Agust,heima,..October08/Term.

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Presentation transcript:

Slides 2-4: Agust,www,....rempi/hcl/October08/HClg3S-V9V ak.ppt & Agust,www,....rempi/hcl/October08/HClg3S-V9V ak.ppt Agust,heima,..October08/Term values for triplet paper kmak.xls Agust,heima,... kennsla/ArnarH/IGOR/Profun ahak.pxp

Spacing between perturbed energy Levels  ) in the 3  - (0 + ), v´=0 state J´(higher)  values for the 3  - (0 + ), v´=0 state  

 E =2B 0 J – 4D 0 J 3 B 0 = cm -1 D 0 = x 10 -3

 E =2B 0 J B 0 = cm -1

Slides 6-7: Agust,www,....rempi/hcl/October08/HClg3S-V9V ak.ppt Agust,heima,... kennsla/ArnarH/IGOR/Profun ahak.pxp

Deperturbed levels according to D. Field et al. Perturbed levels (<= Green et al.) calculated levels: Using W12(v´=9) =266 cm-1 & W12(v´=10) = 589 cm-1 And equation:

Least square W12(9) W12(10) Tryal and error analysis, assuming homogeneous coupling:

=> It is worth checking the effect of V, v´=11 (possibly V,v´=8)